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Aniline is a resonance hybrid of...

Aniline is a resonance hybrid of

A

3 structures

B

6 structures

C

2 structures

D

5 structures

Text Solution

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The correct Answer is:
To determine how many resonance structures aniline has, we will follow these steps: ### Step 1: Draw the Structure of Aniline Aniline is an aromatic amine with the formula C6H5NH2. The structure consists of a benzene ring (C6H5) attached to an amino group (NH2). **Hint:** Remember that aniline has a benzene ring, which is a hexagonal structure with alternating double bonds. ### Step 2: Identify the Lone Pair on the Nitrogen In the amino group (NH2), the nitrogen atom has a lone pair of electrons. This lone pair can participate in resonance with the benzene ring. **Hint:** Identify the lone pair on the nitrogen that can be involved in resonance. ### Step 3: Draw the First Resonance Structure The first resonance structure is the original structure of aniline. The lone pair on nitrogen can form a double bond with the adjacent carbon in the benzene ring, leading to a positive charge on the nitrogen. **Hint:** When drawing resonance structures, ensure that the total number of electrons remains the same. ### Step 4: Draw the Second Resonance Structure In this structure, the lone pair from nitrogen forms a double bond with the carbon atom, resulting in a positive charge on the nitrogen atom. The double bond between the carbon atoms in the benzene ring shifts, creating a new double bond. **Hint:** Focus on how the electrons move; the lone pair on nitrogen creates a new double bond with the carbon. ### Step 5: Draw the Third Resonance Structure The negative charge can shift again, creating another structure where the double bond moves to a different carbon atom in the benzene ring, and the nitrogen retains a positive charge. **Hint:** Keep track of where the positive and negative charges are located as you draw each structure. ### Step 6: Continue Drawing Resonance Structures Repeat the process of shifting the double bonds and the lone pair on nitrogen to create additional resonance structures. You will find that you can create a total of five distinct resonance structures. **Hint:** Each time you draw a new structure, ensure that the overall charge and number of electrons are conserved. ### Conclusion After drawing all possible resonance structures, we find that aniline is a resonance hybrid of **five structures**. **Final Answer:** Aniline is a resonance hybrid of **5 structures**.

To determine how many resonance structures aniline has, we will follow these steps: ### Step 1: Draw the Structure of Aniline Aniline is an aromatic amine with the formula C6H5NH2. The structure consists of a benzene ring (C6H5) attached to an amino group (NH2). **Hint:** Remember that aniline has a benzene ring, which is a hexagonal structure with alternating double bonds. ### Step 2: Identify the Lone Pair on the Nitrogen ...
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