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The completely filled and the completely...

The completely filled and the completely half-filled sub-shells are stable due to

A

symmetrical distribution of electrons

B

exchange energy

C

Both (1) and (2)

D

None of the above

Text Solution

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The correct Answer is:
To answer the question regarding the stability of completely filled and completely half-filled subshells, we can break down the explanation into a step-by-step solution: ### Step-by-Step Solution: 1. **Understanding Electron Configuration**: - In an atom, electrons are arranged in various energy levels and subshells (s, p, d, f). Each subshell can hold a specific number of electrons. A completely filled subshell has the maximum number of electrons it can hold, while a half-filled subshell has exactly half of its capacity filled. 2. **Stability of Electron Configurations**: - Completely filled and half-filled subshells are known to be more stable than other configurations. This stability arises from two main factors: symmetry and exchange energy. 3. **Symmetry in Electron Distribution**: - A completely filled or half-filled subshell exhibits a symmetrical distribution of electrons. For example, in a half-filled p subshell, each of the three p orbitals contains one electron, leading to a balanced and symmetrical arrangement. This symmetry contributes to the overall stability of the atom. 4. **Exchange Energy**: - When electrons are arranged in a symmetrical manner, they can exchange positions without increasing the energy of the system. This phenomenon is known as exchange energy. In a completely filled or half-filled subshell, the electrons can exchange their positions, which leads to a decrease in potential energy. 5. **Lower Energy State**: - Systems tend to be more stable when they are in a lower energy state. The symmetrical arrangement and the resulting exchange energy lower the potential energy of the atom, making it more stable. 6. **Conclusion**: - Therefore, the stability of completely filled and half-filled subshells is due to the symmetrical distribution of electrons and the exchange energy that arises from this arrangement. Both factors contribute to a lower energy state, enhancing the stability of the atom. ### Final Answer: The completely filled and completely half-filled subshells are stable due to: 1. Symmetrical distribution of electrons. 2. Exchange energy resulting from this symmetry. Thus, the correct answer is both 1 and 2.
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The stability of exactly half-filled and completely filled configuration is due to.........and .........

Cu_((aq.))^+ has less stable nature than Cu_((aq.))^(2+) but Fe_((aq.))^(3+) is more stable than Fe_((aq.))^(2+) . Half-filled and completely filled, sub-shell are more stable.

Knowledge Check

  • Assertion: Cu^(2+) (aq) is less than Cu^(3+) (aq) but Fe^(3+) is more stable than Fe^(2+) (aq) Reason : Half filled and completely filled subshells are more stable

    A
    If both assertion and reason are true and the reason is the correct explanation of assertion
    B
    If both assertion and reason are true and the reason is not the correct explanation of assertion
    C
    If assertion is false but reason is true
    D
    If assertion is true but the reason is false
  • The extra stability of half-filled and completely-filled subshell is due to

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    relatively small shielding
    B
    smaller coulombic repulsion enegry
    C
    larger exchange enegry
    D
    all of these
  • Completely filled shells in actinides are

    A
    first two
    B
    first three
    C
    first four
    D
    first five
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