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Preparation of diethyl ether by dehydrat...

Preparation of diethyl ether by dehydration of alcohol is an:

A

`SN^(1)` reaction

B

`SN^(2)` reaction

C

Nucleophilic addition reaction

D

Elimination reaction

Text Solution

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The correct Answer is:
**Step-by-Step Solution:** 1. **Identify the Reaction Type**: The dehydration of alcohol to form diethyl ether is a type of chemical reaction. We need to classify this reaction correctly. 2. **Understand the Reactants**: The reactant in this case is ethyl alcohol (ethanol, C2H5OH). We will be dehydrating this alcohol to form diethyl ether (C2H5OC2H5). 3. **Reaction Conditions**: The reaction typically requires acidic conditions, often using concentrated sulfuric acid (H2SO4) as a catalyst, and is carried out at elevated temperatures (around 413 K). 4. **Mechanism of the Reaction**: - The first step involves protonation of the alcohol (ethanol) by the acid, forming an ethyl oxonium ion (C2H5OH2+). - This oxonium ion is then susceptible to nucleophilic attack by another molecule of ethanol. 5. **Formation of Carbocation**: The protonated alcohol loses a water molecule (H2O), leading to the formation of a carbocation (C2H5+). 6. **Nucleophilic Attack**: The nucleophilic attack occurs when another ethyl alcohol molecule attacks the carbocation, leading to the formation of diethyl ether. 7. **Final Product**: The final product of this reaction is diethyl ether (C2H5OC2H5), and the overall reaction can be summarized as: \[ 2 \text{C}_2\text{H}_5\text{OH} \xrightarrow{\text{H}_2\text{SO}_4, 413 \text{K}} \text{C}_2\text{H}_5\text{O}\text{C}_2\text{H}_5 + \text{H}_2\text{O} \] 8. **Conclusion**: Based on the mechanism and the steps involved, we conclude that the dehydration of alcohol to form diethyl ether is a **nucleophilic substitution reaction**. ---

**Step-by-Step Solution:** 1. **Identify the Reaction Type**: The dehydration of alcohol to form diethyl ether is a type of chemical reaction. We need to classify this reaction correctly. 2. **Understand the Reactants**: The reactant in this case is ethyl alcohol (ethanol, C2H5OH). We will be dehydrating this alcohol to form diethyl ether (C2H5OC2H5). 3. **Reaction Conditions**: The reaction typically requires acidic conditions, often using concentrated sulfuric acid (H2SO4) as a catalyst, and is carried out at elevated temperatures (around 413 K). ...
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Knowledge Check

  • What is the side product obtained during the preparation of diethyl ether by the dehydration of ethyl alcohol with concentrated H_(2)SO_(4) ?

    A
    Ethylene
    B
    Ethane
    C
    Alcohol
    D
    Ethanal
  • Diethyl ether is used as

    A
    Anaesthetic
    B
    Solvent
    C
    Refrigerant
    D
    All
  • The isomer of diethyl ether is

    A
    `(CH_3)_2CHOH`
    B
    `(CH_3)_3C-OH`
    C
    `C_3H_7OH`
    D
    `(C_2H_5)_2CHOH`
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