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The geometry of H2S and its dipole momen...

The geometry of `H_2S` and its dipole moment are:

A

Angular and non-zero

B

Angular and zero

C

Linear and zero

D

Linear and non-zero

Text Solution

AI Generated Solution

The correct Answer is:
To determine the geometry of \( H_2S \) (hydrogen sulfide) and its dipole moment, we can follow these steps: ### Step 1: Identify the central atom The central atom in \( H_2S \) is sulfur (S). **Hint**: Look for the atom that is bonded to the other atoms in the molecule. ### Step 2: Determine the valence electrons Sulfur is in group 16 of the periodic table and has 6 valence electrons. Each hydrogen (H) atom contributes 1 valence electron. Therefore, the total number of valence electrons in \( H_2S \) is: \[ 6 \text{ (from S)} + 1 \times 2 \text{ (from 2 H)} = 8 \text{ valence electrons} \] **Hint**: Count the valence electrons from each atom based on their group number in the periodic table. ### Step 3: Determine the hybridization To find the hybridization, we can use the formula: \[ \text{Hybridization} = \frac{\text{Number of valence electrons}}{2} + \text{Number of lone pairs} \] In \( H_2S \), sulfur has 2 lone pairs (since it has 6 valence electrons and forms 2 bonds with hydrogen). Thus: \[ \text{Hybridization} = \frac{8}{2} = 4 \text{ (which corresponds to sp}^3\text{ hybridization)} \] **Hint**: Remember that each bond and lone pair counts towards the total number of regions of electron density. ### Step 4: Determine the molecular geometry With \( sp^3 \) hybridization, the ideal geometry is tetrahedral. However, due to the presence of 2 lone pairs, the shape of the molecule is bent or angular. **Hint**: Visualize the arrangement of bonds and lone pairs to determine the actual shape. ### Step 5: Analyze the dipole moment In \( H_2S \), sulfur is more electronegative than hydrogen. The bond dipoles from the S-H bonds will not cancel out due to the bent shape of the molecule, resulting in a net dipole moment. **Hint**: Consider the electronegativity of the atoms and the geometry when determining if the dipoles cancel. ### Conclusion The geometry of \( H_2S \) is angular, and it has a non-zero dipole moment due to the asymmetrical distribution of charge. **Final Answer**: The geometry of \( H_2S \) is angular and its dipole moment is non-zero.

To determine the geometry of \( H_2S \) (hydrogen sulfide) and its dipole moment, we can follow these steps: ### Step 1: Identify the central atom The central atom in \( H_2S \) is sulfur (S). **Hint**: Look for the atom that is bonded to the other atoms in the molecule. ### Step 2: Determine the valence electrons ...
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