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In solid-state PC1(5) exists in ionic fo...

In solid-state `PC1_(5)` exists in ionic form. Mark the correct hybridization state of Phosphorus in cationic and anionic form respectively.

A

`d sp ^(2), sp ^(3) d ^(2)`

B

`sp ^(3), sp ^(3) d ^(2)`

C

`sp ^(3) d ^(2), sp ^(3)`

D

`sp ^(3) d ^(2), dsp ^(2)`

Text Solution

Verified by Experts

The correct Answer is:
B
cationic form is `[PCl _(4) ]^(+)` which has `sp ^(3)` hybridization state. And anionic form is `[PCl _(6)]^(-)` which has `sp ^(3) d ^(2)` hybridization state.
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Knowledge Check

  • In the solid state PCl_5 exists as

    A
    `[PCl_4]^(-)` and `[PCl_6]^(+)` ions
    B
    covalent `PCl_5` molecules only
    C
    `[PCl_4]^(+)` and `[PCl_6]^(-)` ions
    D
    covalent `P_2Cl_(10)` molecules only

  • Hybridization in phosphorus in PCl_5 in solid state

    A
    `sp^3`
    B
    `sp^3d^2`
    C
    `sp^3d`
    D
    Both 1 and 2

  • BrF_(3) and IF_(5) both exist in ionic form, in solid state. What are the hybridizations of cationic parts of both, respectively ?

    A
    `sp^(3), sp^(3)`
    B
    `sp^(3)d, sp^(3)d`
    C
    `sp^(3), sp^(3)d`
    D
    `sp^(2), sp^(3)`

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