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tert-Butyl alcohol is much more soluble ...

tert-Butyl alcohol is much more soluble in water than n-butyl alcohol. Explain.

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**Step-by-Step Solution:** 1. **Understanding the Structures**: - Tert-butyl alcohol (2-methyl-2-propanol) has a highly branched structure, while n-butyl alcohol (butan-1-ol) has a straight-chain structure. 2. **Analyzing the Branching**: - The branched structure of tert-butyl alcohol leads to a more compact and spherical shape. This compactness reduces the surface area of the non-polar part of the molecule. ...
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Knowledge Check

  • Which of the following alcohols is the least soluble in water ?

    A
    Ethanol
    B
    1-Propanol
    C
    1-Butanol
    D
    1-Pentanol
  • Ethyl alcohol has much higher boiling point than ether because

    A
    molecular weight of ether is higher
    B
    molecular weight of alcohol is lower
    C
    of hydrogen bonding between the molecules of alcohol
    D
    molecular weight of alcohol is higher
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