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Solution of a weak acid and its anion (t...

Solution of a weak acid and its anion (that is,its conjugate base) or of a base and its common cation are buffered. When we add a small amount of acid or base to any one of the, the pH of solution change very little. pH of buffer solution can be computed as for acidic buffer : `pH=pK_(a)+ log.(["Conjugate base"])/(["Acid"])`
for basic buffer : `pOH=pK_(b)+log.(["Conjugate acid"])/([Base])`
It is generly accepted that a has useful buffer cpacity (pH change resisting power) provided that the value of [salt or conjugate base] /[acid] for acidic buffer lies within the range of 1 : 10 to 1. Buffer capacity is maximum when [conjugate base] = [acid]
one litre of an aqueous solution contains 0.15 mole of `CH_(3)COOH(pK_(a=4.8))` and 0.15 mole of `CH_(3)` COONa. After the addition of 0.05 mole of solid NaOH to this solution, the pH will be :

A

4.5

B

4.8

C

5.1

D

5.4

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Knowledge Check

  • The conjugate base of hydrazoic acid is

    A
    `N^(3-)`
    B
    `N_(3)^(-)`
    C
    `NH_(2)^(-)`
    D
    `NH_(4)^(+)`
  • The conjugate base of hydrazoic acid is

    A
    `N^(3-) `
    B
    ` N_3^(-) `
    C
    `NH_2^(-) `
    D
    ` NH_4^(+) `
  • When 0.02 mole of an alkali is added to an acid buffer , the pH changes from 4.75 to 4.8 the buffer capacity is

    A
    `2.5`
    B
    `0.25`
    C
    `0.4`
    D
    `0.025`
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