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Along which axis the molecular orbital a...

Along which axis the molecular orbital approach each other appropriately, so that a `pi -` bond may form between two `P_x` orbitals containing one unpaired electron?

A

x-axis

B

y-axis

C

z-axis

D

B and C

Text Solution

Verified by Experts

The correct Answer is:
D
Perpendicular axis to x-axis are y-axis & z-axis
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Which p - orbital froms pi - bond ?

Atomic orbitals of bonded atoms combine to form molecular orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals taking part in the bond formation. When two atomic orbitals combine, two molecular orbitals are formed one of which has lower energy than the combining orbitals and is called bonding Molecular Orbital (MO). Whereas the other having higher energy than the two combining atomic orbitals is called Anti Bonding Molecular orbitals (ABMO) The two combining atomic orbitals must have comparable energies and should be properly oriented to allow considerable overlapping. If the overlapping is end to end along internuclear axis, the molecular orbital is called sigma and if the overlapping is lateral 1.e., sidewise the molecular orbital is called pie. Just like atomic orbitals, the molecular orbitals also have varying energy levels. Filling of electrons in molecular orbitals takes place following the same rules as followed for filing of atomic orbitals. The order of filling may not be same for all the molecules or their ions. Bond order is a useful parameter for comparing the various characteristics of molecules. Which of the following pair is expected to have the same bond order ?

Knowledge Check

  • A pi -bond may between two p_x orbitals containing one unpaired electron each when they approach each other appropriately along :

    A
    x-axis
    B
    y-axis
    C
    z - axis
    D
    any direction

  • Which of the following contains one unpaired electron in the 4p orbitals-

    A
    `[Cu(NH_3)_2]^+`
    B
    `[Cu(NH_3)_4]^(2+)`
    C
    `[Cu(CN)_4]^(3-)`
    D
    `[Ni(CN_4)]^(2-)`

  • Atomic orbitals of bonded atoms combine to form molecular orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals taking part in the bond formation. When two atomic orbitals combine, two molecular orbitals are formed one of which has lower energy than the combining orbitals and is called bonding Molecular Orbital (MO). Whereas the other having higher energy than the two combining atomic orbitals is called Anti Bonding Molecular orbitals (ABMO) The two combining atomic orbitals must have comparable energies and should be properly oriented to allow considerable overlapping. If the overlapping is end to end along internuclear axis, the molecular orbital is called sigma and if the overlapping is lateral 1.e., sidewise the molecular orbital is called pie. Just like atomic orbitals, the molecular orbitals also have varying energy levels. Filling of electrons in molecular orbitals takes place following the same rules as followed for filing of atomic orbitals. The order of filling may not be same for all the molecules or their ions. Bond order is a useful parameter for comparing the various characteristics of molecules. Which of the following combinations is not allowed (assume z-axis as the internuclear axis ) ?

    A
    2s and 2s
    B
    `2p_x and 2p_x`
    C
    `2p_z and 2p_z`
    D
    `2p_x and 2p_y`

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    Atomic orbitals of bonded atoms combine to form molecular orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals taking part in the bond formation. When two atomic orbitals combine, two molecular orbitals are formed one of which has lower energy than the combining orbitals and is called bonding Molecular Orbital (MO). Whereas the other having higher energy than the two combining atomic orbitals is called Anti Bonding Molecular orbitals (ABMO) The two combining atomic orbitals must have comparable energies and should be properly oriented to allow considerable overlapping. If the overlapping is end to end along internuclear axis, the molecular orbital is called sigma and if the overlapping is lateral 1.e., sidewise the molecular orbital is called pie. Just like atomic orbitals, the molecular orbitals also have varying energy levels. Filling of electrons in molecular orbitals takes place following the same rules as followed for filing of atomic orbitals. The order of filling may not be same for all the molecules or their ions. Bond order is a useful parameter for comparing the various characteristics of molecules. In which of the following ionization processes, the bond order has increased and the magnetic behaviour has changed ?

    Atomic orbitals of bonded atoms combine to form molecular orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals taking part in the bond formation. When two atomic orbitals combine, two molecular orbitals are formed one of which has lower energy than the combining orbitals and is called bonding Molecular Orbital (MO). Whereas the other having higher energy than the two combining atomic orbitals is called Anti Bonding Molecular orbitals (ABMO) The two combining atomic orbitals must have comparable energies and should be properly oriented to allow considerable overlapping. If the overlapping is end to end along internuclear axis, the molecular orbital is called sigma and if the overlapping is lateral 1.e., sidewise the molecular orbital is called pie. Just like atomic orbitals, the molecular orbitals also have varying energy levels. Filling of electrons in molecular orbitals takes place following the same rules as followed for filing of atomic orbitals. The order of filling may not be same for all the molecules or their ions. Bond order is a useful parameter for comparing the various characteristics of molecules. In the formation of N_2^+ from N_2 , the electron is removed from

    Atomic orbitals of bonded atoms combine to form molecular orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals taking part in the bond formation. When two atomic orbitals combine, two molecular orbitals are formed one of which has lower energy than the combining orbitals and is called bonding Molecular Orbital (MO). Whereas the other having higher energy than the two combining atomic orbitals is called Anti Bonding Molecular orbitals (ABMO) The two combining atomic orbitals must have comparable energies and should be properly oriented to allow considerable overlapping. If the overlapping is end to end along internuclear axis, the molecular orbital is called sigma and if the overlapping is lateral 1.e., sidewise the molecular orbital is called pie. Just like atomic orbitals, the molecular orbitals also have varying energy levels. Filling of electrons in molecular orbitals takes place following the same rules as followed for filing of atomic orbitals. The order of filling may not be same for all the molecules or their ions. Bond order is a useful parameter for comparing the various characteristics of molecules. In the homonuclear diatomic molecule which of the following sets of M.O. orbitals are grade or un-grade

    Atomic orbitals of bonded atoms combine to form molecular orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals taking part in the bond formation. When two atomic orbitals combine, two molecular orbitals are formed one of which has lower energy than the combining orbitals and is called bonding Molecular Orbital (MO). Whereas the other having higher energy than the two combining atomic orbitals is called Anti Bonding Molecular orbitals (ABMO) The two combining atomic orbitals must have comparable energies and should be properly oriented to allow considerable overlapping. If the overlapping is end to end along internuclear axis, the molecular orbital is called sigma and if the overlapping is lateral 1.e., sidewise the molecular orbital is called pie. Just like atomic orbitals, the molecular orbitals also have varying energy levels. Filling of electrons in molecular orbitals takes place following the same rules as followed for filing of atomic orbitals. The order of filling may not be same for all the molecules or their ions. Bond order is a useful parameter for comparing the various characteristics of molecules. The bond order (BO) in B_2 molecule is

    Atomic orbitals of bonded atoms combine to form molecular orbitals. The number of molecular orbitals formed is equal to the number of atomic orbitals taking part in the bond formation. When two atomic orbitals combine, two molecular orbitals are formed one of which has lower energy than the combining orbitals and is called bonding Molecular Orbital (MO). Whereas the other having higher energy than the two combining atomic orbitals is called Anti Bonding Molecular orbitals (ABMO) The two combining atomic orbitals must have comparable energies and should be properly oriented to allow considerable overlapping. If the overlapping is end to end along internuclear axis, the molecular orbital is called sigma and if the overlapping is lateral 1.e., sidewise the molecular orbital is called pie. Just like atomic orbitals, the molecular orbitals also have varying energy levels. Filling of electrons in molecular orbitals takes place following the same rules as followed for filing of atomic orbitals. The order of filling may not be same for all the molecules or their ions. Bond order is a useful parameter for comparing the various characteristics of molecules. Ground state electron configuration of valence shell electrons in nitrogen molecule (N_2) is (sigma_(2s))^2(sigma_(2s)^**)^2(pi_(2px))^2(pi_(2py))^2(pi_(2pz))^2 . Hence the bond order of nitrogen molecule is

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