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Delta H for the reaction H-C-= N(g) + 2...

`Delta H ` for the reaction `H-C-= N(g) + 2H_(2)(g) rarr H - underset(H) underset(|)overset(H ) overset(|)(C) - overset(H) overset(|)(N) - H (g)`
is `- 150 kJ `. Calculate the bond energy of`C -= N`bond.
[ Given bond energies of `C-H= 414 kJ mol^(-1)`, `H-H= 435kJ mol^(-1)`, `C-N = 293kJ mol^(-1)`, `N-H =396 kJ mol^(-1)`]

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To calculate the bond energy of the `C≡N` bond for the given reaction, we can use the following steps: ### Step 1: Write the reaction and identify the bonds The reaction is: \[ H-C \equiv N(g) + 2H_2(g) \rightarrow H_3C-NH_2(g) \] ### Step 2: Identify the bonds in the reactants and products - **Reactants:** - 1 `C≡N` bond - 2 `H-H` bonds (from `2H_2`) - **Products:** - 3 `C-H` bonds (from `H_3C`) - 2 `N-H` bonds (from `NH_2`) ### Step 3: Write the equation for ΔH in terms of bond energies The change in enthalpy (ΔH) can be expressed as: \[ \Delta H = \text{(Sum of bond energies of reactants)} - \text{(Sum of bond energies of products)} \] Given: - ΔH = -150 kJ - Bond energies: - `C-H` = 414 kJ/mol - `H-H` = 435 kJ/mol - `N-H` = 396 kJ/mol - Let the bond energy of `C≡N` = x kJ/mol ### Step 4: Write the equation using bond energies Using the information from the bonds: \[ -150 = [x + 2 \times 435] - [3 \times 414 + 2 \times 396] \] ### Step 5: Simplify the equation Calculating the bond energies: - For reactants: \[ x + 870 \quad \text{(since } 2 \times 435 = 870\text{)} \] - For products: \[ 3 \times 414 + 2 \times 396 = 1242 + 792 = 2034 \] Putting it all together: \[ -150 = [x + 870] - [2034] \] ### Step 6: Rearranging the equation Rearranging gives: \[ -150 = x + 870 - 2034 \] \[ -150 = x - 1164 \] \[ x = -150 + 1164 \] \[ x = 1014 \text{ kJ/mol} \] ### Step 7: Conclusion The bond energy of the `C≡N` bond is: \[ \text{Bond energy of } C≡N = 1014 \text{ kJ/mol} \]

To calculate the bond energy of the `C≡N` bond for the given reaction, we can use the following steps: ### Step 1: Write the reaction and identify the bonds The reaction is: \[ H-C \equiv N(g) + 2H_2(g) \rightarrow H_3C-NH_2(g) \] ### Step 2: Identify the bonds in the reactants and products - **Reactants:** ...
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Delta H for the reaction. HCN(g) + 2H_(2)(g) to CH_(3) NH_(2)(g) is -150 kJ. Calculate the bond energy of -C = N bond. [Given bond energies of C-H = 414 kJ mol^(-1) H-H = 435 kJ mol^(-1) , C-N = 293 kJ mol^(-1) N-H = 396 kJ mol^(-1)

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Knowledge Check

  • Based on the values of B.E. given, Delta_(f)H^(@) of N_(2)H_(4) (g) is : Given : N-N = 159 " kJ mol"^(-1)," "H-H=436 " kJ mol"^(-1) N-=N = 941" kJ mol"^(-1), " "N-H=398 " kJ mol"^(-1)

    A
    711 kJ `" mol"^(-1)`
    B
    62 kJ `" mol"^(-1)`
    C
    `-98 " kJ mol"^(-1)`
    D
    `-711 " kJ mol"^(-1)`
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