Home
Class 11
CHEMISTRY
Statement-1. HF is an electron-deficient...

Statement-1. HF is an electron-deficient hydride.
Statements-2. In HF,F has three lone pairs of electrons.

Text Solution

AI Generated Solution

The correct Answer is:
To address the question, we need to analyze both statements regarding hydrogen fluoride (HF) and determine their validity. ### Step 1: Analyze Statement 1 **Statement 1:** HF is an electron-deficient hydride. - **Explanation:** Hydrogen fluoride (HF) consists of one hydrogen atom and one fluorine atom. In HF, the hydrogen atom shares its single electron with fluorine, forming a covalent bond. However, fluorine is highly electronegative and pulls the shared electron closer to itself, creating a polar covalent bond. This results in the hydrogen atom having a partial positive charge (δ+) and the fluorine atom having a partial negative charge (δ-). - **Conclusion:** Since hydrogen has only one electron and is bonded to a highly electronegative atom (fluorine), it can be considered electron-deficient. Therefore, **Statement 1 is correct**. ### Step 2: Analyze Statement 2 **Statement 2:** In HF, F has three lone pairs of electrons. - **Explanation:** Fluorine (F) has a total of 7 valence electrons. In HF, fluorine uses one of its valence electrons to form a bond with hydrogen, leaving it with 6 electrons. These remaining 6 electrons can be arranged as three lone pairs. - **Conclusion:** Thus, **Statement 2 is also correct**. ### Final Conclusion - **Statement 1:** Correct (HF is indeed an electron-deficient hydride). - **Statement 2:** Correct (Fluorine has three lone pairs of electrons in HF).

To address the question, we need to analyze both statements regarding hydrogen fluoride (HF) and determine their validity. ### Step 1: Analyze Statement 1 **Statement 1:** HF is an electron-deficient hydride. - **Explanation:** Hydrogen fluoride (HF) consists of one hydrogen atom and one fluorine atom. In HF, the hydrogen atom shares its single electron with fluorine, forming a covalent bond. However, fluorine is highly electronegative and pulls the shared electron closer to itself, creating a polar covalent bond. This results in the hydrogen atom having a partial positive charge (δ+) and the fluorine atom having a partial negative charge (δ-). - **Conclusion:** Since hydrogen has only one electron and is bonded to a highly electronegative atom (fluorine), it can be considered electron-deficient. Therefore, **Statement 1 is correct**. ...
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • HYDROGEN

    PRADEEP|Exercise COMPETITION FOCUS (Assertion-Reason Type Questions) Type 2|15 Videos
  • HYDROGEN

    PRADEEP|Exercise COMPETITION FOCUS (Numerical Value Type Questions)|1 Videos
  • HYDROCARBONS

    PRADEEP|Exercise Competition Focus (JEE(main and advanced)/Medical Entrance) VIII. ASSERTION - REASON TYPE QUESTIONS|31 Videos
  • ORGANIC CHEMISTRY-SOME BASIC PRINCIPLES TECHNIQUES

    PRADEEP|Exercise Competition Focus (Jee (Main and Advanced)/Medical Entrance) VIII. Assertion-Reason Type Questions|25 Videos

Similar Questions

Explore conceptually related problems

Assertion NH_(3) is an electron precise hydride. Reason : NH_(3) has one loone pair of electrons on N atom.

Statement I: Sodium hydride can be used as an oxidising agent. Statement II: The lone pair of electrons on nitrogen in pyridine makes it basic. Choose the CORRECT answer from the options given below:

Knowledge Check

  • Electron-deficient hydride is/are

    A
    `BH_(3)`
    B
    `AIH_(3)`
    C
    `BeH_(2)`
    D
    All
  • In which , central atom s has have one lone pair of electron ?

    A
    ` Cl_2`
    B
    ` NH_3`
    C
    `PCl_3`
    D
    `XeF_6`
  • Statement-1: Fluorine has less electron affinity than chlorine. Statement-2 : Due to small size, more electron-electron repulsions are observed in F.

    A
    Statement-1 is True, Statement-2 is True, Statement-2 is a correct explanation for Statement-1
    B
    Statement-1 is True, Statement-2 is True, Statement-2 is NOT a correct explanation for Statement-1
    C
    Statement-1 is True, Statement-2 is False
    D
    Statement-1 is False, Statement-2 is True
  • Similar Questions

    Explore conceptually related problems

    Give an example of electron deficient covalent hydride.

    The hydride that is NOT electron deficient is :

    Which of the following does not have a lone pair of electrons

    In which of the following, the central atoms has two lone pairs of electrons

    In which of the following the central atom has two lone pairs of electrons ?