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In the organic compound CH(2) = CH – CH(...

In the organic compound `CH_(2) = CH – CH_(2) – CH_(2) – C equivCH`, the pair of hydridised orbitals involved in the formation of: `C_(2) – C_(3)` bond is:
`(a) sp – sp_(2) (b) sp – sp_(3) (c) sp_(2 )– sp_(3) (d) sp_(3) – sp_(3)`

Text Solution

Verified by Experts

When both double bonds are present at equivalent positions, double bond is given preference while numbering the carbon chain. Thus, `underset(sp^(2))overset(1)(C)H_(2) = underset(sp^(2))overset(2)(C)H - underset(sp^(3))overset(3)(C)H_(2)-underset(sp^(3))overset(4)(C)H_(2) - underset(sp)overset(5)(C) -= underset(sp)overset(6)(C)H`
`:. C_(2) - C_(3)` bond is formed by overlap of `sp^(2) - sp^(3)` orbitals.
Thus, option (c) is correct.
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Knowledge Check

  • In the organic compound CH_3==CH-CH_2-CH_2--=CH , the parh of hydridised orbitals involved in the fomation of C_2-C_3 bond is

    A
    `sp-sp^2`
    B
    `sp-sp^3`
    C
    `sp^2-sp^3`
    D
    `sp^3-sp^3`
  • Only sp and sp^(2) hybrid orbitals are involved in the formation of :

    A
    `CH_(3)-CH=CH_(2)`
    B
    `CH_(3)-CH_(3)`
    C
    `CH_(3)-C-=CH`
    D
    `H_(2)C=C=CH_(2)`
  • sp^3d^2 hybrid orbitals are

    A
    linear
    B
    pentagonal bipyramidal
    C
    trigonal bipyramidal
    D
    octahedral
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