Home
Class 11
CHEMISTRY
Interpret the non-linear shape of H(2)S ...

Interpret the non-linear shape of `H_(2)S` molecule and non-planar shape of `PCl_(3)` using valence shell electron pair repulsion (VSEPR) theory.
(Atomic number `:H=1, P=15, S=16, Cl=17`)

Text Solution

Verified by Experts

In `H_(2) O ` atomic number of central atom (S) = 16
Electronic arrangment of S = 2, 8, 6
Out of 6 valence eletrons , two electrons are shared with two H atoms and the remaining four electrons are
present as two lone pairs . Thus, we hgave

i.e., it is a molecule of the type `AB_(2)L_(2)` . Due to repulsions between bond pairs and lone pairs the shape is
bent (non-linear).
In `PCl_(3)` atomic number of central atom (P) = 15
Electronic arrangement of P = 2, 8, 5
Out of 5 valence eleectrons , three electrons are shared with three Cl atoms and the remaining 2 electrons are
Present as one lone pair. thus, we have

i.e., it is a molecule of the type `AB_(3) L `. To minimise repulsions between lone pairs bond pairs, the shape
becomes pyramidal (non-planar).
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    PRADEEP|Exercise NCERT EXAMPLAR PROBLEMS (MATCHING TYPE QUESTIONS)|5 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    PRADEEP|Exercise NCERT EXAMPLAR PROBLEMS (ASSERTION AND REASON TYPE QUESTIONS)|3 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    PRADEEP|Exercise NCERT EXAMPLAR PROBLEMS (MULTIPLE CHOICE QUESTIONS -1)|7 Videos
  • APPENDIX

    PRADEEP|Exercise MODEL TEST PAPER <br> (Section C )|9 Videos
  • CLASSIFICATION OF ELEMENTS AND PERIODICITY IN PROPERTIES

    PRADEEP|Exercise Competition Focus (Jee Main and Advanced / Medical Entrance ) ( Assertion - Reason Type Question ) (Type II)|12 Videos

Similar Questions

Explore conceptually related problems

The shape of ClO_3^- according to valence shell electron pair repulsion theory will be

Interpret non-linear shape of H_(2)S and non-planar shape of PCl_(3) on the basis of VSEPR theory.

The approximate shape of a molecule can often be predicted by using what is called the valence-shell electron-pair repulsion (VSEPR) model. Electrons in bonds and in lone pairs can be thought of a ''charge cloud'' that repel one another nad stay as far apart as possible, thus causing molecules to assume specific shapes. The repulsive interactions of electron pairs decrease in the order: Lone pair - Lone pair gt Lone pair - Bond pair gt Bond pair - Bond pair These repulsive effects result in deviations from idealised shapes and alteration in bond angles in molecules. Which among the following molecules have sp^(3)d hybridization with one lone pair of electron on the central atom? (P) SF_(4) (Q) [PCl_(4)]^(+) (R) XeO_(2)F_(2) (S) ClOF_(3)

The approximate shape of a molecule can often be predicted by using what is called the valence-shell electron-pair repulsion (VSEPR) model. Electrons in bonds and in lone pairs can be thought of a ''charge cloud'' that repel one another nad stay as far apart as possible, thus causing molecules to assume specific shapes. The repulsive interactions of electron pairs decrease in the order: Lone pair - Lone pair gt Lone pair - Bond pair gt Bond pair - Bond pair These repulsive effects result in deviations from idealised shapes and alteration in bond angles in molecules. Molecular shape of XeF_(3)^(+),SF_(3)^(+) and CF_(3)^(+) are :

The approximate shape of a molecule can often be predicted by using what is called the valence-shell electron-pair repulsion (VSEPR) model. Electrons in bonds and in lone pairs can be thought of a ''charge cloud'' that repel one another nad stay as far apart as possible, thus causing molecules to assume specific shapes. The repulsive interactions of electron pairs decrease in the order: Lone pair - Lone pair gt Lone pair - Bond pair gt Bond pair - Bond pair These repulsive effects result in deviations from idealised shapes and alteration in bond angles in molecules. Which of the following statements is incorrect?

The approximate shape of a molecule can often be predicted by using what is called the valence-shell electron-pair repulsion (VSEPR) model. Electrons in bonds and in lone pairs can be thought of a ''charge cloud'' that repel one another nad stay as far apart as possible, thus causing molecules to assume specific shapes. The repulsive interactions of electron pairs decrease in the order: Lone pair - Lone pair gt Lone pair - Bond pair gt Bond pair - Bond pair These repulsive effects result in deviations from idealised shapes and alteration in bond angles in molecules. Which of the following statement is correct with respect ot bond angles?

The approximate shape of a molecule can often be predicted by using what is called the valence-shell electron-pair repulsion (VSEPR) model. Electrons in bonds and in lone pairs can be thought of a ''charge cloud'' that repel one another nad stay as far apart as possible, thus causing molecules to assume specific shapes. The repulsive interactions of electron pairs decrease in the order: Lone pair - Lone pair gt Lone pair - Bond pair gt Bond pair - Bond pair These repulsive effects result in deviations from idealised shapes and alteration in bond angles in molecules. Among the following molecules. (P) XeO_(3)" (Q)"XeOF_(4) (R) XeO_(2)F_(2)" (S)"XeF_(5) Those having different molecular geometry but same number of lone pairs on Xe are :

The space model which is obtained by joining the points representing various bonded atoms gives the shape of the molecule. The geometry of the molecule is definite relative arrangement of the bonded atoms in a molecule. The shape and geometry of a molecule is explained by valence shell electron pair repulsion theory given by Gillespie and Nyholm. Which molecule has both shape and geometry identical ? (I) SnCl_(2) " " (II) NH_(3) " " (III) PCl_(5) " " (IV) SF_(6)

The space model which is obtained by joining the points representing various bonded atoms gives the shape of the molecule. The geometry of the molecule is definite relative arrangement of the bonded atoms in a molecule. The shape and geometry of a molecule is explained by valence shell electron pair repulsion theory given by Gillespie and Nyholm. Select the correct code for the following repulsion orders, according to VSEPR theory : (I) lone pair -lone pair gt lone pair-bond pair (II) lone pair-bond pair gt bond pair -bond pair (III) lone pair -lone pair gt bond pair-bond pair (IV) lone pair - bond pair gt lone pair-lone pair

PRADEEP-CHEMICAL BONDING AND MOLECULAR STRUCTURE-NCERT EXAMPLAR PROBLEMS (SHORT ANSWER QUESTIONS)
  1. Interpret the non-linear shape of H(2)S molecule and non-planar shape ...

    Text Solution

    |

  2. Using molecular orbital theory, compare the bond energy and magnetic c...

    Text Solution

    |

  3. Explain the shape of BrF(5^.)

    Text Solution

    |

  4. Structrues of moleculars of two compounds are shown on the side . (...

    Text Solution

    |

  5. Why does type of overlap given in the following figure not result in b...

    Text Solution

    |

  6. Explain why PCl(5) is trigonal bipyramidal whereas IF(5) is square pyr...

    Text Solution

    |

  7. In both water and dimethyl ether (CH(3)-underset(..)overset(..)O-CH(3)...

    Text Solution

    |

  8. Write Lewis structure of the following compounds and show format charg...

    Text Solution

    |

  9. The energy of sigma2p(z), molecular orbital is greater than pi2p(x) an...

    Text Solution

    |

  10. What is the effect of the following processes on the bond order of N(2...

    Text Solution

    |

  11. Give reasons for the following : (i) Covalent bonds are directional...

    Text Solution

    |

  12. What is an ionic bond ? With two suitable examples, explain the difere...

    Text Solution

    |

  13. Arrange the following bonds in order of increasing ionic character giv...

    Text Solution

    |

  14. Explain why CO(3)^(2-) ion cannot be represented by a single Lewis str...

    Text Solution

    |

  15. Predict the hybridisation of each carbon in the molecule of organic co...

    Text Solution

    |

  16. Group the following as linear and non-linear molecules : H(2)O,HOCl,...

    Text Solution

    |

  17. Elements X,Y and Z have 4,5 and 7 valence electrons respectively, (i) ...

    Text Solution

    |

  18. Draw the resonating structure of (i) Ozone molecule (ii) Nitrate i...

    Text Solution

    |

  19. Presict the shapes of the following molecules on the basis of hybridis...

    Text Solution

    |

  20. All the C-O bonds in carbonate in (CO(3)^(2-)) are equal in length. Ex...

    Text Solution

    |