Home
Class 12
CHEMISTRY
Define limiting molar conductivity. Why ...

Define limiting molar conductivity. Why does conductivity of an electrolyte decrease with discrease in concentration.

Text Solution

Verified by Experts

The molar conductivity of a solution at infinite dilution, i.e., when concentration approaches zero is called limiting molar conductivity. With decrease in concentration, i.e., with dilution, number of ions per `cm^(3)` decreases due to large increase in volume of the solution. as conductivity is the conductance per `cm^(3)` of the solution, hence it decreases.
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    PRADEEP|Exercise NCERT QUESTIONS AND EXERCISES WITH ANSWER|15 Videos
  • ELECTROCHEMISTRY

    PRADEEP|Exercise NCERT EXERCISES|16 Videos
  • ELECTROCHEMISTRY

    PRADEEP|Exercise TEST YOUR GRIP (FILL IN THE BLANKS)|29 Videos
  • D- AND F-BLOCK ELEMENTS

    PRADEEP|Exercise IMPORTANT QUESTIONS|30 Videos
  • GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS

    PRADEEP|Exercise Curiosity Questions|2 Videos

Similar Questions

Explore conceptually related problems

(a) Following reactions occur at cathode during the electrolysis of aqueous silver chloride solution : Ag+ (aq) + e^(-) to Ag (s), E° = + 0.80 V H^(+) (aq) + e^(-) to 1/2H_(2)(g) ,E^(@) = 0.00 V On the basis of their standard reduction electrode potential (E°) values, which reaction is feasible at the cathode and why? (b) Define limiting molar conductivity. Why conductivity of an electrolyte solution decreases with the decrease in concentration ?

Molar conductivity decreases with decrease in concentration

Knowledge Check

  • Limiting molar conductivity of NaBr is

    A
    `Lambda_m^@NaBr = Lambda_m^@NaCl + Lambda_m^@KBr`
    B
    `Lambda_m^@NaBr = Lambda_m^@ NaCl + Lambda_m^@KBr - Lambda_m^@KCl`
    C
    `Lambda_m^@NaBr=Lambda_m^@NaOH + Lambda_m^@NaBr - Lambda_m^@NaCl`
    D
    `Lambda_m^@NaBr=Lambda_m^@NaCl-Lambda_m^@NaBr`
  • The molar conductivity of strong electrolyte

    A
    Increases on dilution slightly
    B
    Does not change on dilution
    C
    Decreases on dilution
    D
    Depends on density of electrolyte itself
  • Similar Questions

    Explore conceptually related problems

    Why does the conductivity of a solution decrease with dilution ?

    Why does the conductivity of a solution decrease with dilution ?

    Why does the conductivity of a solution decrease with dilution?

    Why does the conductivity of a solution decrease with dilution ?

    Why does the conductivity of a solution decreases with dilution ?

    Define conductivity and molar conductivity for a solution of an electrolyte.