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Crossed Aldol Condensation...

Crossed Aldol Condensation

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Crossed Aldol Reaction and Condensations

Aldol condensation reaction takes place in aldehydes having alpha-hydrogen with a dilute base to yield β-hydroxy aldehydes known as aldols. This condensation reaction is most commonly referred to as aldol condensation. Now, if the condensation reaction exists between two different carbonyl compounds, then it is known as crossed aldol condensation.

What is the Aldol Condensation Reaction?

It can be defined as an organic reaction in which enolate ion (the anion formed when alpha hydrogen in the molecule of an aldehyde or a ketone is removed as a hydrogen ion) reacts with a carbonyl compound to form beta-hydroxy ketone or beta-hydroxy aldehyde, which afterwards undergoes dehydration to yield a conjugated enone.

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Knowledge Check

  • Assertion : Cross aldol condensation of ethanal and propanal gives a mixture of four products. Reason : Ethanal and propanal, both contain alpha - hydrogen atom.

    A
    If both assertion and reason are true and reason is the correct explanation of assertion.
    B
    If both assertion and reason are true but reason is not the correct explanation of assertion.
    C
    If assertion is true but reason is false.
    D
    If both assertion and reason are false.
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    Cross aldol condensation occurs between

    Cross aldol condensation occurs between

    Cross aldol condensation occurs between

    Describe the following : (i) Acetylation (ii) Cannizzaro reaction (iii) Cross aldol condensation (iv) Decarboxylation

    Describe the following: (a) Wolff Kishner reduction (b) Clemmensen reduction (c) Cross aldol condensation

    Describe the following i. Acetylation ii. Cannizzaro reaction iii. Cross aldol condensation iv. Decarboxylation

    (a) Illustrate the following reactions giving a suitable example for each. (i) Cross aldol condensation (ii) Decarboxylation (b) Give simple tests to distinguish between the following pairs of compound (i) Pentan-2-one and pentan-3-one (ii) Benzaldehyde and Acetophenone (ii) Phenol and Benzoic acid