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While sulphate dioxide and hydrogen perx...

While sulphate dioxide and hydrogen perxide can act as oxidising as well as reducing agents in their reactions, ozone and nitric acid act only as oxidants. Why?

Text Solution

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a. In `SO_(2)`, oxidation number of `S` is `+4`. In principle `S` can have a minimum oxidation number of `-2` and maximum of `+6`. Therefore, `S` in `SO_(2)` can either decrease or increase its oxidation number and hence can act both as an oxidising as well as a reducing agent.
b. In `H_(2)O`, the oxidation number of `O` is `-1`. In principle, `O` can can have a minimum oxidation number of `-2` and maximum of zero `(+2 " is possible only with " OF_(2))`. Therefore, `O` in `H_(2)O_(2)` can either decrease its oxidation number from `-1` to `-2` or can increase its oxidation number from `-1` to `0`. Therefore, `H_(2)O_(2)` acts as an oxidising as well as a reducing agent.
c. In `O_(3)` the oxidation number of `O` is zero. It can only decrease its oxidation number from from `0` to `-1` or `-2`, but cannot increase to `+2`. Therefore, `O_(3)` acts only as an oxidant.
d. In `HNO_(3)`, oxidation number of `N` is `+5` which is maximum. Therefore, it can only decrease its oxidation number and hence it acts as an oxidant only.
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Knowledge Check

  • Oxide of nitrogen which acts as oxidising as well as reducing agent is

    A
    NO
    B
    `N_2O_5`
    C
    `NO_2`
    D
    `N_2O`
  • Which one can act as oxidising & reducing agent

    A
    `HNO_(3)`
    B
    `H_(2)O_(2)`
    C
    `H_(2)SO_(3)`
    D
    `H_(2)SO_(4)`
  • Which one can act as oxidising & reducing agent

    A
    `HNO_(3)`
    B
    `H_(2)O_(2)`
    C
    `H_(2)SO_(3)`
    D
    `H_(2)SO_(4)`
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