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The order in which the following oxides ...

The order in which the following oxides are arranged according to decreasing basic nature is

A

`Na_(2)O,MgO,Al_(2)O_(3),CuO`

B

`CuO,Al_(2)O_(3),MgO,Na_(2)O`

C

`Al_(2)O_(3),CuP,MgO,Na_(2)O`

D

`CuO,MgO,Na_(2)O_(3)

Text Solution

Verified by Experts

The correct Answer is:
D

Applying Fajans' rule,the lower the charge,the more is ionic and the more is basic and vice versa.Moreover,small cation,large anion,high charge and presence of d electrons mean more covalant and more acidic. Therefore,decreasing order of basic nature is `{:(,+1,,+2,,+3,,+2),(,Na_(2)O, gt , MgO, gt,Al_(2)O_(3),gt,CuO),("Group-",1,,2,,13,,11),("Period-",3rd,,3rd,,3rd,,4th):} `
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