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When CH(3)Cl undergoes homolytic bond-fi...

When `CH_(3)Cl` undergoes homolytic bond-fission

A

carbon undergoes a geometric changed from tetrahedral to planar

B

hybridisation changed from `sp^(3) "to" sp^(2)`

C

Both of these takes place

D

None of the above

Text Solution

Verified by Experts

The correct Answer is:
C
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Answer the following : (a) How many types of fission are possible of a covalent bond? (b) how many types of ions are formed by heterolytic fission and what are their names? (c) What are the names and nature of the parts formed by homolytic fission? (d) How many electrons are present in the valence shell of the carbon atom of the carbonium ion? (e) How many electrons are present in the valence shell of carbon atom of the carbanion ion? (f) Name the attacking reagents and give their nature. (g) Write the names of the parts obtained when C-Cl bond of ethyl chloride undergoes heterolytic fission. (h) What is the major factor that influences the relatives stabilities of carbocations, carbanions and free radicals.

CH_(3)CH_(2)Cl undergoes homolytic fission, produces

Knowledge Check

  • CH_(3)CH_(2)Cl undergoes homolytic fission produces

    A
    `CH_(3)overset(*)(C)H_(2)` and `overset(*)(C)l`
    B
    `CH_(3)overset(o+)(C)H_(2)` and `Cl^(Θ)`
    C
    `CH_(3)overset(o+)(C)H_(2)` and `overset(*)(C)l`
    D
    `CH_(3)overset(*)(C)H_(2)` and `Cl^(Θ)`

  • CH_(3)CH_(2)Cl undergoes homolytic fission to produce

    A
    `CH_(3)CH_(2) and overset(.)Cl`
    B
    `CH_(3)overset(+)CH_(2) and Cl^(-)`
    C
    `CH_(3)overset(+)CH_(2) and overset(.)Cl`
    D
    `CH_(3)overset(.)CH_(2) and Cl^(-)`

  • CH_(3)CH_(2)Cl undergoes homolytic fission produces:

    A
    `CH_(3)overset(.)CH_(2) and Cl^(.)`
    B
    `CH_(3)overset(+)CH_(2) and Cl^(-)`
    C
    `CH_(3)overset(+)CH_(2) and Cl^(.)`
    D
    `CH_(3)overset(.)CH_(2) and Cl^(-)`

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    When CH_(3)Cl undergoes alkaline hydrolysis to produce CH_(3)OH , the state of hybridization of C atom in the transition state is

    In CH_3OH the bond that undergoes heterolytic fission most readily is

    The correct order for homolytic bond dissociation energies ( Delta H in kcal/mol) for CH_(4)(A), C_(2)H_(6)(B) and CH_(3)Br(C) is

    CH_(3)-.^(2)underset(._(1)CH_(2)-H)underset(|)overset(H)overset(|)C-.^(3)overset(H)overset(|)CH-._(4)CH_(2)-H, C_(1)-H,C_(2)-H,C_(3)-H and C_(4)-H the homolytic bond dissociation energy is in the order :

    In which of the following homolytic bond fission takes place ?

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