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When CH(3)Cl undergoes homolytic bond-fi...

When `CH_(3)Cl` undergoes homolytic bond-fission

A

carbon undergoes a geometric changed from tetrahedral to planar

B

hybridisation changed from `sp^(3) "to" sp^(2)`

C

Both of these takes place

D

None of the above

Text Solution

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The correct Answer is:
C
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CH_(3)CH_(2)Cl undergoes homolytic fission to produce

CH_(3)CH_(2)Cl undergoes homolytic fission produces:

CH_(3)CH_(2)Cl undergoes homolytic fission, produces

In CH_3OH the bond that undergoes heterolytic fission most readily is

Answer the following : (a) How many types of fission are possible of a covalent bond? (b) how many types of ions are formed by heterolytic fission and what are their names? (c) What are the names and nature of the parts formed by homolytic fission? (d) How many electrons are present in the valence shell of the carbon atom of the carbonium ion? (e) How many electrons are present in the valence shell of carbon atom of the carbanion ion? (f) Name the attacking reagents and give their nature. (g) Write the names of the parts obtained when C-Cl bond of ethyl chloride undergoes heterolytic fission. (h) What is the major factor that influences the relatives stabilities of carbocations, carbanions and free radicals.

CH_(3)-.^(2)underset(._(1)CH_(2)-H)underset(|)overset(H)overset(|)C-.^(3)overset(H)overset(|)CH-._(4)CH_(2)-H, C_(1)-H,C_(2)-H,C_(3)-H and C_(4)-H the homolytic bond dissociation energy is in the order :

Knowledge Check

  • CH_(3)CH_(2)Cl undergoes homolytic fission produces

    A
    `CH_(3)overset(*)(C)H_(2)` and `overset(*)(C)l`
    B
    `CH_(3)overset(o+)(C)H_(2)` and `Cl^(Θ)`
    C
    `CH_(3)overset(o+)(C)H_(2)` and `overset(*)(C)l`
    D
    `CH_(3)overset(*)(C)H_(2)` and `Cl^(Θ)`

  • CH_(3)CH_(2)Cl undergoes homolytic fission to produce

    A
    `CH_(3)CH_(2) and overset(.)Cl`
    B
    `CH_(3)overset(+)CH_(2) and Cl^(-)`
    C
    `CH_(3)overset(+)CH_(2) and overset(.)Cl`
    D
    `CH_(3)overset(.)CH_(2) and Cl^(-)`

  • CH_(3)CH_(2)Cl undergoes homolytic fission produces:

    A
    `CH_(3)overset(.)CH_(2) and Cl^(.)`
    B
    `CH_(3)overset(+)CH_(2) and Cl^(-)`
    C
    `CH_(3)overset(+)CH_(2) and Cl^(.)`
    D
    `CH_(3)overset(.)CH_(2) and Cl^(-)`
    • MHTCET PREVIOUS YEAR PAPERS AND PRACTICE PAPERS-BASIC PRINCIPLES AND TECHNIQUES IN ORGANIC CHEMISTRY-EXERCISE 2
    1. When CH(3)Cl undergoes homolytic bond-fission

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    2. Which one of the following C-H bonds is the wekest for homolytic fissi...

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    3. In which of the following ways does the hydride ion tend to function ?

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    4. Most stable radical is

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    5. Select the incorrect statement .

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    6. Dehydrobromination (-HBr) of the following in increasing order is

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    7. The structural formula of 2-oxo-3-methyl-(N-bromo) butanamide is

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    8. Indicate the wrongly named compound

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    9. The most stable carbanion is

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    10. The most stable free radical among the following is

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    11. CH(3) overset(*) H(2) disproportionates to

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    12. Additionof HCI to 3,3 dimethyl but-1-ene yields two products, one of w...

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    13. Basic strength of CH-=overset(Theta)C(l), CH(2)=overset(Theta) CH(II) ...

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    14. Electrophile overset(o+)(NO(2)) attacks the following In which ca...

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    15. Major organic product fomred from the following sequence of reactions ...

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    16. Among the following, which is least acidic ?

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    17. In which of the following compounds, does the substituent not exert it...

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    18. When acidified sodium extract of organic compound is treated with acet...

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    19. The formation of yellow precipitate by the addition of solution of amm...

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    20. In Carius tube, the compound ClCH(2)COOH was heated with fuming HNO(3)...

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