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Discuss the molecular shape of "BrF"(3) ...

Discuss the molecular shape of `"BrF"_(3)` on the basis of VSEPR theory.

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The central atom Br has seven electrons in the valence shell. Three of these will form electron pair bonds with three fluorine atoms leaving behind four electrons. Thus, there are three bond pairs and two lone pairs. According to VSEPR theory, these will occupy the corners of a trigonal bipyramid. The two lone pairs will occupy the equatorial positions to minimise lone pair-lone pair and the bond pair-lone pair repulsions which are greater than the bond pair-bond pair repulsions. In addition, the axial flourine atoms will be bent towards the equatorial fluorine in order to minimise the lone pair-lone pair repulsions. The shape would be that of a slightly bent T.
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Knowledge Check

  • The shape of BrF_(3)

    A
    Linear
    B
    Bent (T ) shaped
    C
    Square pyramidal
    D
    Pentaganal bi pyramidal
  • The number of CO ligands that can be attached to Fe(Z=26) on the basis of EAN theory are

    A
    5
    B
    6
    C
    10
    D
    12
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