Home
Class 12
CHEMISTRY
Arrange the following compounds in the o...

Arrange the following compounds in the order of decreasing molar conductivity in aqueous solution.
`i.a. K[Co(NH_(3))_(2)(NO_(2))_(4)]`
`b. [Cr(NH_(3))_(3)(NO_(2))_(3)]`
`c." " [Cr(NH_(3))_(5)(NO_(2))]_(3)[Co(NO_(2))_(6)]_(2)`
`d." "[Mg(Cr(NH_(3)(NO_(2))_(5)]`
`ii. a. Li[Co(NH_(3))_(2)(NO_(2))_(4)]" "b." "Na[Co(NH_(3))_(2)(NO_(2))_(4)]`
` c.K[Co(NH_(3))_(2)(NO_(2))_(4)]" "d." "Cs[Co(NH_(3))_(2)(NO_(2))_(4)]`
`iii. a. Pt(NH_(3))_(6)Cl_(4)"" b." " Cr(NH_(3))_(6)Cl_(3)`
`c." " Co(NH_(3))_(4)Cl_(3)" "d. K_(2)PtCl_(6)`

Text Solution

Verified by Experts

Since coordination number `(C.N)` of `Pt^(4+) =6`
`:.[Pt(NH_(3))_(6)]CI_(4)implies5ions`
(b) `CN` of `Cr^(3+) =6`
`:. [Cr(NH_(3))_(6)]CI_(3)implies4ions`
(c ) `CN` of `Co^(3+) =6`
`:.[Co(NH_(3))_(4)CI_(2)]implies2 ions`
(d) `K_(2)[PtCI_(6)]implies 3 ions`
Increasing order of conductane is
`cltdltblta` .
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • COORDINATION COMPOUNDS

    CENGAGE CHEMISTRY|Exercise Ex 7.1 Subjective (Isomerism In Coordination Compounds)|6 Videos
  • COORDINATION COMPOUNDS

    CENGAGE CHEMISTRY|Exercise Ex 7.1 Objective (Terminology)|16 Videos
  • COORDINATION COMPOUNDS

    CENGAGE CHEMISTRY|Exercise Ex 7.1 Subjective (Effective Atomic Number (Ean))|3 Videos
  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY|Exercise Archives Subjective|23 Videos
  • D AND F BLOCK ELEMENTS

    CENGAGE CHEMISTRY|Exercise Archives Subjective|29 Videos

Similar Questions

Explore conceptually related problems

Arrange the following compounds in order of increasing molar conductivity . (i) K[Co(NH_(3))_(2)(NO_(2))_(4)]" " (ii) [Cr(NH_(3))_(3)(NO_(2))_(3)] (iii) [Cr(NH_(3))_(5)(NO_(2))]_(3)[Co(NO_(2))_(6)]_(2)" " (iv) [Cr(NH_(3))_(6)]Cl_(3)

Arrange the following compounds in order of increasing molar conductivity (a) K[Co(NH_(3))_(2)(NO_(2)_(4)] (b) [Cr(NH_(3))_(3)(NO_(2))_(3)] (c) [Cr(NH_(3))_(5)(NO_(2))]_(3)[Co(NO_(2))_(6)]_(2) (d) Mg[Cr(NH_(3))(NO_(2))_(5)]

Knowledge Check

  • [Co(NH_(3))_(4)(NO_(2))_(2)]Cl exhibits.

    A
    linkage isomerism, ionization isomerism and geometrical isomerism
    B
    ionization isomerism, geometrical isomerism and optical isomerism
    C
    linkage isomerism, geometrical isomerism and optical isomerism
    D
    linkage isomerism, ionization isomerism and optical isomerism
  • [Co(NH_(3))_(4)(NO_(2))_(2)]Cl exhibits

    A
    ionization isomerism, geometrical isomerism and optical isomerism
    B
    linkage isomerism, geometrical isomerism and optical isomerism
    C
    linkage isomerism, ionization isomerism and optical isomerism
    D
    linkage isomerism, ionization isomerism and geometrical isomerism
  • [Co(NH_(3))_(4)(NO_(2))_(2)]CI exhibits

    A
    linkage isomerism, geometrical isomerism, and opical isomerism
    B
    linkage isomerism, ionization isomerism and optical isomerism
    C
    linkage isomerism, ionization isomerism and geometrical isomerism
    D
    ionization isomerism, geometrical isomerism and optical isomerism.
  • Similar Questions

    Explore conceptually related problems

    Arrange the following complexes in the increasing order of their molar conductivity : (a) K[Co(NH_(3))_(2)(NO_(2))_(4)] (b) [Cr(NH_(3))_(5)(NO_(2))]_(3)[Co(NO_(2))_(6)]_(2) (c ) Mg[Cr(NH_(3))(NO_(2))_(5)] (d) [Cr(NH_(3))_(3)(NO_(2))_(3)]

    Arrange the following complexes in the increasing order of conductivity of their solution : [Co(NH_(3))_(3)Cl_(3)],[Co(NH_(3))_(4)Cl_(2)]Cl,[Co(NH_(3))_(6)]Cl_(3),[Cr(NH_(3))_(5)Cl]Cl_(2) .

    [Co(NH_(3))_(5)NO_(2)]SO_(4) shows

    [Co(NH_(3))_(4)(NO_(2))_(2)]Cl exhibits:

    IUPAC name [Co(NH_(3))_(5)(NO_(2))]Cl_(2) is