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Arrange the following compounds in the o...

Arrange the following compounds in the order of decreasing molar conductivity in aqueous solution.
`i.a. K[Co(NH_(3))_(2)(NO_(2))_(4)]`
`b. [Cr(NH_(3))_(3)(NO_(2))_(3)]`
`c." " [Cr(NH_(3))_(5)(NO_(2))]_(3)[Co(NO_(2))_(6)]_(2)`
`d." "[Mg(Cr(NH_(3)(NO_(2))_(5)]`
`ii. a. Li[Co(NH_(3))_(2)(NO_(2))_(4)]" "b." "Na[Co(NH_(3))_(2)(NO_(2))_(4)]`
` c.K[Co(NH_(3))_(2)(NO_(2))_(4)]" "d." "Cs[Co(NH_(3))_(2)(NO_(2))_(4)]`
`iii. a. Pt(NH_(3))_(6)Cl_(4)"" b." " Cr(NH_(3))_(6)Cl_(3)`
`c." " Co(NH_(3))_(4)Cl_(3)" "d. K_(2)PtCl_(6)`

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Text Solution

Verified by Experts

Since coordination number `(C.N)` of `Pt^(4+) =6`
`:.[Pt(NH_(3))_(6)]CI_(4)implies5ions`
(b) `CN` of `Cr^(3+) =6`
`:. [Cr(NH_(3))_(6)]CI_(3)implies4ions`
(c ) `CN` of `Co^(3+) =6`
`:.[Co(NH_(3))_(4)CI_(2)]implies2 ions`
(d) `K_(2)[PtCI_(6)]implies 3 ions`
Increasing order of conductane is
`cltdltblta` .
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Arrange the following compounds in the order of decreasing molar conductivity in aqueous solution. i.a. K[Co(NH_(3))_(2)(NO_(2))_(4)] b. [Cr(NH_(3))_(3)(NO_(2))_(3)] c." " [Cr(NH_(3))_(5)(NO_(2))]_(3)[Co(NO_(2))_(6)]_(2) d." "[Mg(Cr(NH_(3)(NO_(2))_(5)] ii. a. Li[Co(NH_(3))_(2)(NO_(2))_(4)]" "b." "Na[Co(NH_(3))_(2)(NO_(2))_(4)] c.K[Co(NH_(3))_(2)(NO_(2))_(4)]" "d." "Cs[Co(NH_(3))_(2)(NO_(2))_(4)] iii. a. Pt(NH_(3))_(6)Cl_(4)"" b." " Cr(NH_(3))_(6)Cl_(3) c." " Co(NH_(3))_(4)Cl_(3)" "d. K_(2)PtCl_(6)

How can be the following pair of isomers be distinguished from one another
I `[Co(NH_(3))_(6)][Cr(NO_(2))_(6)]` and
(II) `[Cr(NH_(3))_(6)][Co(No_(2))_(6)]`
I `[Cr(NH_(3))_(6)[Cr(No_(2))_(6)]` and (II) `[Cr(NH_(3))_(4)(No_(2))_(2)][Cr(NH_(3))_(2)(NO_(2))_(4)]` .

Arrange the following compounds in order of increasing molar conductivity . (i) K[Co(NH_(3))_(2)(NO_(2))_(4)]" " (ii) [Cr(NH_(3))_(3)(NO_(2))_(3)] (iii) [Cr(NH_(3))_(5)(NO_(2))]_(3)[Co(NO_(2))_(6)]_(2)" " (iv) [Cr(NH_(3))_(6)]Cl_(3)

[Co(NH_(3))_(4)Cl_(2)]NO_(2) and [Co(NH_(3))_(4)Cl.NO_(2)]Cl are " …................" isomers

Name the type of isomerism exibited by the following isomers :
(1) `[Cr(NH_(3))_(6)][Cr(CN)_(6)] and [Cr(NH_(3))_(4)(CN)_(2)][Cr(NH_(3))_(2)(CN)_(4)]`
(2) `[Co(py)_(2)(H_(2)O)_(2)Cl_(2)]Cl and [Co(py)_(2)(H_(2)O)Cl_(3)]H_(2)O`
(3) `[Pt(NH_(3))_(4)Br_(2)]Cl_(2) and [Pt(NH_(3))_(4)Cl_(2)]Br_(2)`
(4) `[Co(NH_(3))_(5)NO_(2)]Cl_(2) and [Co(NH_(3))_(5)ONO]Cl_(2)`

Arrange the following compounds in order of increasing molar conductivity (a) K[Co(NH_(3))_(2)(NO_(2)_(4)] (b) [Cr(NH_(3))_(3)(NO_(2))_(3)] (c) [Cr(NH_(3))_(5)(NO_(2))]_(3)[Co(NO_(2))_(6)]_(2) (d) Mg[Cr(NH_(3))(NO_(2))_(5)]

`[Cr(NH_(3))_(4)Cl_(2)]NO_(3)` का नाम है -

`[Co(NH_(3))_(4)Cl_(2)] NO_(2)` एवं `[Co(NH_(3))_(4)Cl(NO_(2))]Cl` समावयवी है-

Arrange the following compounds in order of increasing molar conductivity
(a) `K[Co(NH_(3))_(2)(NO_(2))_(4)]`
(b) `[Cr(NH_(3))_(3)(NO_(2))_(3)]`
(c) `[Cr(NH_(3))_(5)(NO_(2))]_(3)[Co(NO_(2))_(6)]_(2)`
(d) `Mg[Cr(NH_(3))(NO_(2))_(5)]`

Which of the following options representions the oxdation state of Co and Cr in the given complex ? [CO(NH_(3))_(4)(NO_(2))_(2)][Cr(NH_(3))_(3)(NO_(2))_(3)]

Arrange the following compounds in the order of decreasing molar conductivity in aqueous solution. a. K[Co(NH_(3))_(2)(NO_(2))_(4)] b. [Cr(NH_(3))_(3)(NO_(2))_(3)] c." " [Cr(NH_(3))_(5)(NO_(2))]_(3)[Co(NO_(2))_(6)]_(2) d." "[Mg(Cr(NH_(3)(NO_(2))_(5)]

Arrange the following compounds in the order of decreasing molar conductivity in aqueous solution.
`a. K[Co(NH_(3))_(2)(NO_(2))_(4)]`
`b. [Cr(NH_(3))_(3)(NO_(2))_(3)]`
`c." " [Cr(NH_(3))_(5)(NO_(2))]_(3)[Co(NO_(2))_(6)]_(2)`
`d." "[Mg(Cr(NH_(3)(NO_(2))_(5)]`

Arrange the following compounds in the order of decreasing molar conductivity in aqueous solution. a. K[Co(NH_(3))_(2)(NO_(2))_(4)] b. [Cr(NH_(3))_(3)(NO_(2))_(3)] c." "[Mg(Cr(NH_(3)(NO_(2))_(5)]

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