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how will you distinguish between the following pairs of isomers `[Cr(NH_(3))_(3)(NO_(2))_(3)]` and `[Cr(NH_(3))_(6)][Cr(NO_(2))_(6)]`

Text Solution

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By conductane measurement Its isomer will have nearly zero molar conductane while latter isomer has two ions and will show molar conductane for `2` ions .
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How do you distinguish between the following pairs of isomers? [Cr(NH_(3))_(5)Br]CI and [Cr(NH_(3))_(5)CI]Br [CO(NH_(3))_(6)][Cr(NO_(2))_(6)] and [Cr(NH_(3))_(6)] [CO(NO_(2))_(6)]

How do you distinguish between the following pairs of isomers? [Cr(NH_(3))_(5)Br]CI and [Cr(NH_(3))_(5)CI]Br [CO(NH_(3))_(6)][Cr(NO_(2))_(6)] and [Cr(NH_(3))_(6)] [CO(NO_(2))_(6)]

Knowledge Check

  • The compexes [Co(NH_(3))_(6)][Cr(C_(2)O_(4))_(3)] and [Cr(NH_(3))_(6)][Co(C_(2)O_(4))_(3)]

    A
    Geometrical isomerism
    B
    Linkage isomerism
    C
    Coordination isomerism
    D
    Ionization isomerism

  • [Co(NH_(3))_(6)][Cr(CN)_(6)] and [Cr(NH_(3))_(6)][Co(CN)_(6)] present an example of

    A
    linkage isomerism
    B
    ionisation isomerism
    C
    coordination isomerism
    D
    solvate isomerism

  • The number of geometrical isomers of [Co(NH_(3))_(3)(NO_(2))_(3)] are

    A
    4
    B
    3
    C
    2
    D
    0

    • Similar Questions

    Explore conceptually related problems

    How will you distinguish between the following isomer pairs ? (a) (i) [Cr(H_(2)O)_(6)]Cl_(3) and (ii) [Cr(H_(2)O)_(5)Cl]Cl_(2)H_(2)O (b) (i) cis [Pt (NH_(3))_(2)Cl_(2)] and (ii) trans [Pt(NH_(3))_(2)Cl_(2)] (c ) The two enantiomers of [CoCl_(2)(en)_(2)]^(+)

    Describe a simple test to distinguish between the following pairs of compounds (i) (A) [Co(NH_(3))_(5)Br]SO_(4) and (B) [Co(NH_(3))_(5)SO_(4)]Br (ii) (A) [Cr(H_(2)O)_(6)]CI_(3) and (B) [Cr (H_(2)O)_(5)CI] CI_(2)H_(2)O (iii) (A) cis [PtCI_(2)(NH_(3))_(2)] and (B) trans [Pt CI_(2)(NH_(3))_(2)] (iv) (A) and (B) Two enantiomers of [Co(en)_(2)(NH_(3))_(2)] (V) (A) (A) [Cr (NH_(3))_(6)][Cr(NH_(3))_(2)(NO_(2))_(4)] (vi) (A) [Pt(NH_(3))_(2)CI_(2)] and (B) [Pt(NH_(3))_(6)]CI_(2) (vii) (A) [Co(NH_(3))_(5)CI]SO_(4) and (B) [Co(NH_(3))_(5)SO_(4)]CI .

    How can be the following pair of isomers be distinguished from one another I [Co(NH_(3))_(6)][Cr(NO_(2))_(6)] and (II) [Cr(NH_(3))_(6)][Co(No_(2))_(6)] I [Cr(NH_(3))_(6)[Cr(No_(2))_(6)] and (II) [Cr(NH_(3))_(4)(No_(2))_(2)][Cr(NH_(3))_(2)(NO_(2))_(4)] .

    Name the type of isomerism exibited by the following isomers : (1) [Cr(NH_(3))_(6)][Cr(CN)_(6)] and [Cr(NH_(3))_(4)(CN)_(2)][Cr(NH_(3))_(2)(CN)_(4)] (2) [Co(py)_(2)(H_(2)O)_(2)Cl_(2)]Cl and [Co(py)_(2)(H_(2)O)Cl_(3)]H_(2)O (3) [Pt(NH_(3))_(4)Br_(2)]Cl_(2) and [Pt(NH_(3))_(4)Cl_(2)]Br_(2) (4) [Co(NH_(3))_(5)NO_(2)]Cl_(2) and [Co(NH_(3))_(5)ONO]Cl_(2)

    The complexes |Co(NH_(3))_(6)||Cr(C_(2)O_(4))_(3)| and |Cr(NH_(3))_(6)||Co(CrO_(4))_(3)| are

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