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Two research students were instruced int...

Two research students were instruced intructed to synthesise the complex
`[Co(NH_(3))_(5)(NO_(2))]Br_(2)`
They synthesised the complexes with identical molecular formula molar mass geometry conductane and spin but they differed in colour Based on the above facts answer the following questions
Complexes synthesised can be
(i) `[Cr(NH_(3))_(5)(NO_(2))Br_(2)`,(ii) `[Cr(NH_(3))_(5)(ONO)]Br_(2)`
(iii) `[Cr(NH_(3))_(5)Br_(2)]NO_(2)` (iv) All of these .

A

Both(i) and (ii)

B

Both(i) and(iii)

C

Both(ii)and(iii)

D

All of these

Text Solution

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The correct Answer is:
A
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Write the IUPAC name of (i) [Co(NH_(3))_(5)NO_(2)]Cl_(2) (ii) [Cr(H_(2)O)_(5)SCN]^(2+) (iii) [CoCl(NO_(2))(en)_(2)]^(+)

What type isomerism is shown by the complex [Co(NH_(3))_(5)NO_(2)]Cl_(2) ?

Knowledge Check

  • Two research students were instruced intructed to synthesise the complex [Co(NH_(3))_(5)(NO_(2))]Br_(2) They synthesised the complexes with identical molecular formula molar mass geometry conductane and spin but they differed in colour Based on the above facts answer the following questions The difference in colour is due to

    A
    optical isomerism
    B
    geometrical isomerism
    C
    linkage isomerism
    D
    nuclear isomerism

  • Two research students were instruced intructed to synthesise the complex [Co(NH_(3))_(5)(NO_(2))]Br_(2) They synthesised the complexes with identical molecular formula molar mass geometry conductane and spin but they differed in colour Based on the above facts answer the following questions Which of the ligands can show ambidentate property ?

    A
    `NO_(2)^(Θ)`
    B
    `NH_(3)`
    C
    `H_(2)O`
    D
    `CO_(3^(2-)`

  • The pair [Co(NH_(3))_(4)Cl_(2)]Br_(2) and [Co(NH_(3))_(4)Br_(2)]Cl_(2) will show

    A
    Linkage isomerism
    B
    Hydrate isomerism
    C
    Ionization isomerism
    D
    Coordinate isomerism

    • Similar Questions

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    The complex ions [Co(NH_(3))_(5)(NO_(2))^(2+) and [Co(NH_(3))_(5)(ONO)]^(2+) are called

    The complex ions [Co(NH_(3))_(5)(NO_(2))]^(2+) and [Co(NH_(3))_(5)(ONO)]^(2+) are called

    Consider the following isomers. (i) [Pt (NH_(3))_(4)Cl_(2)]Br_(2) " " (ii) [Pt (NH_(3))_(4) Br_(2)]Cl_(2) (iii) [Co(NH_(3))_(4)Cl_(2)] NO_(2) Which of the following observations is correct ?

    [Cr(NH_(3))_(5)NO_(2)]SO_(4) and [Cr(NH_(3))_(5)ONO]SO_(4) are related to each other as: .

    [Co(NH_(3))_(5)NO_(2)]Cl_(2) and [Co(NH_(3))_(5)ONO]Cl_(2) are related to each other as :

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