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Cations are classified into varius group...

Cations are classified into varius group on the basis of their behaviour against some reagents .The group reagent used for the classifaction of most common cation are `HCI,H_(2)S,NH_(4)OH,(NH_(4))_(2)CO_(3)` Classification is based on whether a cation reacts with these reagents by the formation of precipitates or not .
An aqueous solution contain `Hg^(2+),Hg_(2)^(2+),Pb^(2+)`.THe addition of `2M HCI` will procipitate.

A

`HgCI_(2)`only

B

`PbCI_(2)"only"^(-)`

C

`PbCI_(2)` and `Hg_(3)CI_(2)`

D

`PbCI_(2)` and `CdCI_(2)`

Text Solution

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The correct Answer is:
c

`2M MCI` is group reagent for reagent for group 1 cation `PbCI_(2)` And `HgCI_(2)` will get precipitated, is their solubility products `(K_(sp))` are less than that of other radical
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CENGAGE CHEMISTRY-QUALITATIVE INORGANIC SALT ANALYSIS-Exercises (Linked Comprehension)
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  2. Find out (F)

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  4. Cations are classified into varius group on the basis of their behav...

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  6. The reagents like AgNO(3),K(4)[Fe(CN)(6)],KCNS,KI,K(2)CrO(4) Nessler's...

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  7. The reagents like AgNO(3),K(4)[fe(CN)(6)],KCNS,KI,K(2)CrO(4) Nessler's...

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  8. The reagents like AgNO(3),K(4)[Fe(CN)(6)],KCNS,KI,K(2)CrO(4) Nessler's...

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  9. NH(3) solution was added to four semple solution in difference test t...

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  10. NH(3) solution was added to four semple solution in difference test t...

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  11. NH(3) solution was added to four semple solution in difference test t...

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  12. (A) is a colourless solid, it metal when heated and gives of a gas (...

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  13. (A) is a colourless solid, it metal when heated and gives of a gas (...

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  14. (A) is a colourless solid, it metal when heated and gives of a gas (...

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  15. compound (B) on strong heating produces compound(s) which has/have

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  16. Which of the following statement is/are correct for gas (D) ? (I)it h...

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  17. Compound (B) on reaction with [Na(en)(3)][NO(3))(2) gives a coloured ...

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  18. A colourless (A) when place into water a heavy white turbidly of (B) s...

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  19. A colourless (A) when place into water a heavy white turbidly of (B) s...

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