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Why is K(a2)ltltK(a1) for H2SO4 in water...

Why is `K_(a_2)ltltK_(a_1)` for `H_2SO_4` in water?

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`H_2SO_4` ionises in two steps and hence has two dissociation constants, i.e., `H_2SO_4` acts as a dibasic acid.
(a). `H_2SO_4+H_2OtoHSO_4^(ɵ)+H_3O^(o+)` `K_(a_1)`
(b). `HSO_4^(ɵ)+H_2OtoSO_4^(2-)+H_2O^(o+)` `K_(a_2)`
`K_(a_1)ltK_(a_1)` because the negatively charged `HSO_4^(ɵ)` ion has much less tendency to donate a proton as compared to netural `H_2SO_4`.
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CENGAGE CHEMISTRY-APPENDIX INORGANIC VOLUME 2-Short Answer Type
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  6. Why do some metals occur in the native state?

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  10. What is the name given to solid phase of earth?

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  11. Give one example where hydrometallurgy is used for metal extraction?

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  12. Name the method of metal refining which is generally used when a metal...

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  18. What do you understand by roasting in presence of NaCl?

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  19. Why NF3 cannot be hydrolysed, while NCl3 can be readily hydrolysed?

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  20. Why NI5 does not exist While PCl5 exists?

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  21. Why the boiling point of ammonia is greater than phosphine?

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