Home
Class 11
CHEMISTRY
Which of the following reaction would un...

Which of the following reaction would undergo Diels-Alder reaction ?
.

A

All

B

`(II), (III), (IV)`

C

`(III), (IV)`

D

`(II)`

Text Solution

Verified by Experts

The correct Answer is:
C

For Diels-Alder reaction, dienes should have `EDG` and dienophile should have `EWG` So `(I)` does not react.
(II) Diene (buta-1,3-diene) has s-trans conformation, so does not react
(III) Undergoes Diels-Alder reaction.
(IV) Undergoes intramolecular Diels-Alder reaction.
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • ORGANIC REACTION MECHANISM

    CENGAGE CHEMISTRY|Exercise Assertion-Reasoning|12 Videos
  • ORGANIC REACTION MECHANISM

    CENGAGE CHEMISTRY|Exercise Archives|8 Videos
  • ORGANIC REACTION MECHANISM

    CENGAGE CHEMISTRY|Exercise Multiple Correct|30 Videos
  • NCERT BASED EXERCISE

    CENGAGE CHEMISTRY|Exercise Chemical Equilibrium|72 Videos
  • P-BLOCK GROUP 13 - BORON FAMILY

    CENGAGE CHEMISTRY|Exercise Exercise Archives (Subjecive)|9 Videos

Similar Questions

Explore conceptually related problems

Explain why neither of the following compounds undergoes Diels - Alder reaction with dienophile (e.g. maleic anhydride ). a. HC-=C-C-=CH b. c.

Which of the following compounds would undergo cannizzaro reaction ? Benzaldehyde, Cyclohexanone , 2-mehtylpentanal.

Knowledge Check

  • Which of the following compounds would undergo Diels-Alder reaction with dienophile (e.g., Maleic anhydride) ?

    A
    `HC -= C - C -= CH`
    B
    C
    D
  • Which of the following reactions would give caproic acid ?

    A
    `n-C_5 H_11 Br overset ((i) Mg//ether) underset((ii) CO_2) rarr`
    B
    `n-C_5 H_11 Li overset ((i) CO_2) underset((ii) H_3 O) rarr`
    C
    `n-C_(4)H_(9)Br underset({:((i)CO_(2)),((iii)H_(3)O^(o+)):})overset((i)Mg//"ether")(to)`
    D
    `n-C_5 H_11 MgBr + (CN)_2 overset((i) Delta) underset((ii) H_3 O^(oplus))rarr`
  • Which of the following reactions would give propanal ?

    A
    Ethyl propanoate + DBAH (diisobutyl aluminium hydride). `[(i-C_(4)H_(9))_(2)AlH)]` at `-70^(@)C`, followed by hydrolysis.
    B
    Propyl propanoate `+ DIBAL-H//H_(2)O`
    C
    Ethyl cyanide `+ DBAH`
    D
    Propanoyl chloride `+ LBAH`
  • Similar Questions

    Explore conceptually related problems

    Which of the following reactions will undergo an elimination reaction and an alkene will be formed in the product ?

    Which of the following reactions would give trans-alkene ? .

    Which of the following compounds would undergo Cannizzaro's reaction

    Which of the following compounds would undergo Cannizzaro's reaction

    Which of the following compounds will undergo Cannizzaro reaction ?