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Which of the following reactions are cor...

Which of the following reactions are correct ?

A

B

(A) (trans) `underset(SN^(1))overset(overset(Theta)(OH))to(B)(cis)`

C

D

`(A) (trans) overset(H_(2)O)underset(SN^(1))to(C)(trans)`

Text Solution

Verified by Experts

The correct Answer is:
A, C

In (a) `SN^2` reaction proceeds by inversion of configuration, so the product is cis.
In polar solvent (e.g., `H_2 O`), `SN^1` reaction occurs, and reaction and racemisation take place if bond to the asymmetric `C` atom is broken.
So the correct answer for `SN^1` reaction is `(c)`.
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CENGAGE CHEMISTRY-ORGANIC REACTION MECHANISM-Multiple Correct
  1. Which of the following reactions are correct ?

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  2. Which of the following reactions would give racemised and retention pr...

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  3. Which of the following statements are correct statements ?

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  4. In which of the following species containing both nucleophile and leav...

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  5. Which of the following statements are correct ?

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  6. Which of the following are SN^2 reactions ?

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  7. Vinyl bromide undergoes :

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  8. The halogen atom in RX can easily be replaced by nucleophiles such as ...

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  9. Which of the following statements are correct ?

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  10. Which of the following reactions represents SN reaction ?

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  11. Which of the following reactions are feasible ?

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  12. Which of the following transformations are feasible ?

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  13. In which of the following reactions, the intermediate species acyl nit...

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  14. Which of the following statements are correct ?

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  15. Which of the following is//are the rate determining step (s) of the gi...

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  16. The products in the given reaction are : .

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  17. Which of the following statements are correct about the addition of HB...

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  18. Which of the following statements are correct ?

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  19. In which of the following reactions, rearrangement is possible ?

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  20. Which of the following is an example of nucleophilic addition to aceta...

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