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Which of the following pairs give positi...

Which of the following pairs give positive Tollens test?

A

Glucose, Sucrose

B

Glucose, fructose

C

Hexanal, acetophenone

D

Fructose,sucrose

Text Solution

Verified by Experts

The correct Answer is:
B

Glucose is an aldehyde, gives positive Tollens test. Fructose although ketone gives positive Tollens test because under the basic conditions of the reagent, fructose undergoes a rearrangement to form glucose and mannose `(C-2 "epimer of glucose")`.
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Knowledge Check

  • Which of the following pairs give positive Tollen's test ?

    A
    Glucose, sucrose
    B
    Glucose, fructose
    C
    Hexanal, acetophenone
    D
    Fructose, sucrose
  • Which of the following pair give positive Tollen's Test ?

    A
    Glucose, sucrose
    B
    Glucose, fructose
    C
    Hexanol,Acetophenone
    D
    Fructose,sucrose
  • Which of the following will give positive tollen's test ?

    A
    `CH_(3)-CH_(3)`
    B
    `CH_(2)=CH_(2)`
    C
    `CH-=CH`
    D
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