Home
Class 11
CHEMISTRY
Calculate the resonance enegry of N(2)O ...

Calculate the resonance enegry of `N_(2)O` form the following data
`Delta_(f)H^(Theta) of N_(2)O = 82 kJ mol^(-1)`
Bond enegry of `N-=N, N=N, O=O,` and `N=O` bond is `946, 418, 498`, and `607 kJ mol^(-1)`, respectively.

Text Solution

Verified by Experts

For `N_(2)O,N_(2)+(1)/(2)O_(2) rarr N_(2)O, DeltaH_(exp)=82kJ`
Also from bond energy data, using `N=N=O` structure for `N_(2)O`
`DeltaH_(f cal. ) =-[1(N=N)+1(N=O)]+[(N-=N)+(1)/(2)(O=O)]`
`-[418+607]+[946+(1)/(2)(498)]=+170kJ`
Now resonance energy
`=Exp .DeltaH_(f N_(2)O)-`Calcu lated `DeltaH_(f N_(2)O)`
`=82-170=-88kJ mol^(-1)`
Promotional Banner

Topper's Solved these Questions

  • THERMOCHEMISTRY

    P BAHADUR|Exercise Exercise 24|1 Videos
  • THERMOCHEMISTRY

    P BAHADUR|Exercise Exercise 25|1 Videos
  • THERMOCHEMISTRY

    P BAHADUR|Exercise Exercise 22|1 Videos
  • REDOX REACTIONS

    P BAHADUR|Exercise Exercise(8) Statement:Explanation type problems|19 Videos
  • THERMODYNAMICS

    P BAHADUR|Exercise Exercise|232 Videos

Similar Questions

Explore conceptually related problems

Calculate the resonance energy of N_(2)O from the following data : DeltaH_(f)^(@) of N_(2)O = 82 kJ mol^(-1) , Bond energies of N equivN , N = N , O =O and N =O bonds are 946, 418, 498 and 607 kJ mol^(-1) respectively.

Calculate the resonance energy of N_(2)O from the following data: DeltaH_(1)^(@) of N_(2)O = 82 kJ "mole"^(-1) . Bond energies N=N = 946 kJ "mole"^(-1) N=N = 418 kJ "mole"^(-1) O=O = 498 kJ "mole"^(-1) N=O = 607 kJ "mol"^(-1)

Calculate the resonance energy of N_(2)O from the following data: DeltaH_(1)^(@) of N_(2)O = 82 kJ "mole"^(-1) . Bond energies N=N = 946 kJ "mole"^(-1) N=N = 418 kJ "mole"^(-1) O=O = 498 kJ "mole"^(-1) N=O = 607 kJ "mole"^(-1)

Calculate the resonance enegry of NO_(2) ( :O-N=O: ) The measured enthalpy formation of NO_(2)(Delta_(f)H^(Theta)) is 34 kJ mol^(-1) . The bond energies given are: N -O rArr 222 kJ mol^(-1) N -= N rArr 946 kJ mol^(-1) O = O rArr 498 kJ mol^(-1) N = O rArr 607 kJ mol^(-1)