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BF(3) and NF(3) both molecules, are cova...

`BF_(3) and NF_(3)` both molecules, are covalent, but `BF_(3)` is non - polar and `NF_(3)` is polar.Its reason is

A

Boron is a solid and nitrogen is a gas in free state

B

`BF_(3)` is planner but `NF_(3)` is pyramidal in shap

C

Boron is a metalloid while nitrogen is a non-metal

D

Atomic size of boron is smaller than that of nitrogen

Text Solution

Verified by Experts

The correct Answer is:
b

`BF_(3)` is planar, hence the dipole moment of the molecule is zero `NF_(3)` is pyramidal, thus it posses dipole moment Hence `NF_(3)` is a pole compounds
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BF_(1) and NF_(3) both molecules, are covalent, but BF_(3) is non - polar and NF_(3) pole. Its reason is

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A polar covalent bond with positive and negative charge centres at its ends is called a dipole. The polarity of a dipole is measured by its dipole moment. Mathematically it is expressed as dipole moment, mu=q xx d where q and d are the net charge and the distance between the two charges respectively. Dipole moment is a vector quantity. The net dipole moment of a polyatomic molecule is the resultant of the various bond moments present in the molecule. The values of dipole moment are expressed in Debye (D) or in SI units in terms of coulomb- metre (Cm). One of the most important applications of dipole moment is in the determination of geometry and shape of molecules besides prediction of a number of properties of the molecules. The molecules BF_3 and NH_3 both are covalent compounds but BF_3 is non-polar while NF_3 is polar . The reason is that

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A2Z-CHEMICAL BONDING AND MOLECULAR STRUCTURE-Valence Bond Theory (Vbt)
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  2. In which of the following sepcies , is the underlined carbon has sp^3 ...

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  3. Among the following the compounds , the one that is polar and has cent...

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  4. The bond between two identical non-metal atoms has a pair of electrons...

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  5. Which of the following will provide the most efficient overlap?

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  6. The number and type of bonds between two carbon atoms in CaC(2) are:

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  7. Which is not true according to VBT?

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  8. The hybridisation of C atoms in (C - C) single-bond of H - C -= C - CH...

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  9. Number of sigma bonds in P4 O(10) is :

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  10. The bond in the formation of fouorine molecule will be

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  11. Which of the following are wrong?

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  12. Which of the following overlaps gives a sigma bond with x as internucl...

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  13. Which of the statement is correct about SO(2)?

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  14. Which p-orbitals overlapping would give the strongest bond?

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  15. Ratio of sigma and pi bonds is maximum in

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  16. Which of the following is True stetement?

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  17. HCN and HNC moleculas have equal number of

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  18. Allyl cyanide has

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  19. Mg(2)C(1) reacts with water forming propyne C(3)^(4-) has

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  20. The strength of bonds by overlapping of atomic orbitals is in order

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