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Assertion: Benzaldehyde is more reactive...

Assertion: Benzaldehyde is more reactive than ethanal towards nucleophilic attact.
Reason : The overall effect of- `l` and `+R` effect of phenyl group decrease the electron density on the carbon atom of `gtC = O` group in benzaldehyde.

A

If Both assertion and reason are true reason is the correct explation of the assertion.

B

If Both assertion and reason are true but reason is not the correct explation of the assertion.

C

If assertion is true but reason is false.

D

If assertion is false but reason is true.

Text Solution

Verified by Experts

The correct Answer is:
A
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Knowledge Check

  • Assertion: Benzaldehyde is less reactive than ethanal towards nucleophilic attach. ltbr. Reason: All the carbon atoms of benzaldehyde are sp^(2) -hybridized.

    A
    if both assertion and reson are true, and reason is the true explanation of the assertion.
    B
    If both assertion and reason are true, but reason is not the true explanation of the assertion.
    C
    if assertion is true, but reason is false.
    D
    If both assertion and reason are false.
  • Assertion (A): Benzaldehyde is less reactive than ethanal towards nucleophilic addition reactions. Reason (R): Ethanal is more sterically hindered.

    A
    Both A and Rare true and R is the correct explanation of A
    B
    Both A and R are true but R is NOT the correct explanation of A
    C
    A is true but R is false
    D
    A is false and R is true
  • Assertion. Propene is more reactive than ethene towards electrophilic addition reactions Reason. Hyperconjugation effect of the CH_3 group increases the electron density in the double bond

    A
    If both assertion and reason are true, and reason is the true explanation of the assertion.
    B
    If both assertion and reason are true, but reason is not the true explanation of the assertion.
    C
    If assertion is true, but reason is false.
    D
    If both assertion and reason are false
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    Assertion : Anhydrides are more reactive than ester for nucleophilic substitution Reason : R.COO– is better leaving group than R–O–

    Assertion: Phenol is more reactive than benzene towards electrophilic reactions. Reason : The +R effect of OH group increases the electron density on benzene nucleus.

    Assertion: Acetanilide is more reactive than aniline towards electrophilic substitution reactions. Reason: The activating effect of NHCOCH_3 is less than that of amino group

    Assertion (A) Benzaldehyde is less reactive in comparison to ethonal towards nucleophilic attack. Reason (R ) All the carbon atoms of benzaldehyde are sp^(2) - hybridised.

    (A) p-methoxy benzaldehyde is less recative than bensaldehyde towards cyanohydrin formation. (R) The +R effect methoxy group increases the electron deficiency of the carbonyl carbon.