Home
Class 12
CHEMISTRY
In the following reaction order , B is ...

In the following reaction order , B is
`CH_(3)CH_(2)COOH overset (P//Br_(2)) to A overset (alc KOH) underset (H^(+)) to B`

A

`CH_(2)=CH-COOH`

B

`CH_(2)-underset(Br)underset(|)(CH)-COOH`

C

`CH_(3)CH_(2)COBr`

D

`CH_(3)CH_(2)CH_(2)OH`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we will analyze the reactions taking place in the given sequence. ### Step 1: Identify the starting compound The starting compound is **CH₃CH₂COOH**, which is propanoic acid (a carboxylic acid). **Hint:** Recognize the functional groups and structure of the starting compound. ### Step 2: Understand the first reaction The first reaction involves **CH₃CH₂COOH** reacting with **P/Br₂**. This is known as the **Hale–Volhard–Zelinsky (HVZ) reaction**. In this reaction, the alpha-hydrogen of the carboxylic acid is replaced by a bromine atom. **Hint:** Recall that in HVZ reaction, bromination occurs at the alpha position of carboxylic acids. ### Step 3: Perform the HVZ reaction In the HVZ reaction, the alpha-hydrogen (the hydrogen attached to the carbon adjacent to the carboxylic acid) is replaced by bromine. Thus, the product A formed from this reaction will be **CH₃CHBrCOOH**. **Hint:** Identify the position of the alpha-hydrogen and understand how it is replaced by bromine. ### Step 4: Identify the second reaction The next step involves treating product A (**CH₃CHBrCOOH**) with **alc KOH** (alcoholic potassium hydroxide) followed by hydrolysis. This step typically leads to an elimination reaction. **Hint:** Remember that alcoholic KOH promotes elimination reactions, leading to the formation of alkenes. ### Step 5: Perform the elimination reaction In the elimination reaction, the bromine atom and a hydrogen atom from the adjacent carbon are removed, resulting in the formation of a double bond. The product formed will be **CH₂=CHCOOH**, which is **acrylic acid**. **Hint:** Visualize the elimination process to see how the double bond is formed. ### Conclusion The final product B after the reactions is **CH₂=CHCOOH** (acrylic acid). **Final Answer:** Product B is **CH₂=CHCOOH** (acrylic acid). ---

To solve the problem step by step, we will analyze the reactions taking place in the given sequence. ### Step 1: Identify the starting compound The starting compound is **CH₃CH₂COOH**, which is propanoic acid (a carboxylic acid). **Hint:** Recognize the functional groups and structure of the starting compound. ### Step 2: Understand the first reaction ...
Promotional Banner

Topper's Solved these Questions

  • ALDEHYDES, KETONES AND CARBOXYLIC ACID

    A2Z|Exercise Assertion-Reasoning Questions|7 Videos
  • ALDEHYDES, KETONES AND CARBOXYLIC ACID

    A2Z|Exercise Section D - Chapter End Test|30 Videos
  • ALDEHYDES, KETONES AND CARBOXYLIC ACID

    A2Z|Exercise AIPMT/NEET Questions|43 Videos
  • ALCOHOLS, PHENOLS AND ETHERS

    A2Z|Exercise Section D - Chapter End Test|30 Videos
  • BIOMOLECULES

    A2Z|Exercise Section D - Chapter End Test|30 Videos

Similar Questions

Explore conceptually related problems

End product of the following reaction is CH_(3)CH_(2)COOH overset(Cl_(2))underset(red P)to overset("alcoholic KOH")to

What are A and B in the following sequence of reactions : CH_(3)CH_(2)COOHunderset(Br_(2))overset(P)rarrA, (ii) Aunderset((ii)H^(+))overset((i)Alc.KOH"excess")rarrB

Complete the following reactions : CH_(3)CH_(2)Br overset(Alc . KOH)to

The compound B is : CH_(3)CH_(2)COOH overset(Cl_(2))underset(red P)rarrAoverset(Alc. KOH)rarrB

The compound A , B and C in the reaction sequence CH_(3) - CH_(2) OH overset(PBr_(3))to A overset(Alc. KOH) to B overset(Br_(2))to C are given by the set :

The compound A , B and C in the reaction sequence CH_(3) - CH_(2) OH overset(PBr_(3))to A overset(Alc. KOH) to B overset(Br_(2))to C are given by the set :

A2Z-ALDEHYDES, KETONES AND CARBOXYLIC ACID-AIIMS Questions
  1. In the following reaction order , B is CH(3)CH(2)COOH overset (P//Br...

    Text Solution

    |

  2. Strongest acid among the following is

    Text Solution

    |

  3. Aldehydes and keton can be distinguished by

    Text Solution

    |

  4. The above reaction is

    Text Solution

    |

  5. The intermediate formed in aldol condensation is

    Text Solution

    |

  6. In the reaction C(6)H(5)CHO + C(6)H(5)NH(2) rarr C(6)H(5)N rarr CHC(...

    Text Solution

    |

  7. The compound most suitable for the preparation of cyanohydrin is

    Text Solution

    |

  8. Among the following the strongest acid is

    Text Solution

    |

  9. At higher temperature, iodoform reaction is given by the dilute soluti...

    Text Solution

    |

  10. The regent used for the sepration of acetaldehyde from acetophenone is

    Text Solution

    |

  11. o-Toluic acid on reaction with Br(2) + Fe gives

    Text Solution

    |

  12. CH(3) CO(2) C(2) H(5) on reaction with sodium ethoxide in ethanol give...

    Text Solution

    |

  13. The following sequence of reaction on Agives

    Text Solution

    |

  14. Isopropylbenzne on air oxidation in the presence of dilute acid gives

    Text Solution

    |

  15. The product obtained is//are

    Text Solution

    |

  16. Benzoic acid is treat with lithum aluminium hydride.

    Text Solution

    |

  17. CH(3)CH(2)C = N overset (X) to CH(3)CH(2)OH The compound X is

    Text Solution

    |

  18. Which of these compound is synthesised by chloral?

    Text Solution

    |

  19. Prologed exposure of far or oil in moist air and light causes had smel...

    Text Solution

    |

  20. 3-hydroxybutanal formed when X reacts whith Y in dilute Z solution. Wh...

    Text Solution

    |