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van der Waal's equation reduces itself t...

van der Waal's equation reduces itself to the ideal gas equation at

A

high pressure and low temperature

B

low pressure and low temperature

C

low pressure and high temperature

D

high pressure alone

Text Solution

Verified by Experts

The correct Answer is:
C

At low pressure , the distance between the molecules is large. At high temperatures , these molecules are moving wit great speeds. Under these conditions , intermolecular interactions are minimum. Thus , a real gas behaves like an ideal gas and the van der Waals equation reduces itself to the ideal gas equation.
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Van Der Waals Equation

A gas described by van der Waal's equation (i) behaves similar to an ideal gas in the limit of large molar volume (ii) behaves similar to an ideal gas in the limit of large pressure (iii) is characterised by van der Waal's coefficients that are dependent on the identity of the gas but are independent of the temperature (iv) has the pressure that is lower than the pressure exerted by the same gas behaving ideally

Knowledge Check

  • The gases obey the different gas laws only theoretically. Practically all of them show some deviation from these laws. These are called real gases. The deviation are maximum under high pressyre and at low temperature. These are comparatively small when the conditions are reversed. It has been found that the easily liquefiable gases show more deviations from the ideal gas beheviour as compared to the gases which are liqufied with diffculty. The van der Waals equation reduces itself to ideal gas equation at

    A
    high pressure and low temperature
    B
    low pressure and low temperature
    C
    low pressure and high temperature
    D
    high pressure only.
  • The vander waal's equation of state reduces itself to the idea gas equation at

    A
    high pressure and low temperature
    B
    low pressure and low temperature
    C
    low pressure and high temperature
    D
    high pressure and high temperature
  • van der Waal's equation is true for

    A
    Ideal gas
    B
    Real gas
    C
    Gaseous substance
    D
    None of the above
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