Home
Class 11
CHEMISTRY
Which of the following species behave bo...

Which of the following species behave both as a nucleophile and an electrophile?
(i) `CH_(3)C=N:` , (ii) `CH_(4)`
(iii) `H_(2)C=O` , (iv) `H_(2)`

A

(ii), (iii)

B

(i), (ii)

C

(iii), (iv)

D

(ii), (iv)

Text Solution

Verified by Experts

The correct Answer is:
A

`CH_(3)CN` and `H_(2)CO` at as both nucleophilic and electrophilic because `C` atom in each of these species is pibonded to highly electronegative atom, `N` and `O`, respectively. Being partially positively charged, `C` is an electrophilic site. On the other hand, the electronegative `N adn O` atoms having unshared `e^(-)` pairs are nucleophilic sites.
`CH_(4) and H_(2)` are neither nucleophilic nor electrophilic.
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • GENERAL ORGANIC CHEMISTRY

    R SHARMA|Exercise Follow- up Test 6|10 Videos
  • GENERAL ORGANIC CHEMISTRY

    R SHARMA|Exercise Follow- up Test 7|11 Videos
  • GENERAL ORGANIC CHEMISTRY

    R SHARMA|Exercise Follow- up Test 4|7 Videos
  • EQUILIBRIUM

    R SHARMA|Exercise ARCHIVES|69 Videos
  • ISOMERISM

    R SHARMA|Exercise Archives|11 Videos

Similar Questions

Explore conceptually related problems

Classify the following molecules I ions as nucleophiles or electrophiles : HS^(-), BF_(3), CH_(3) CH_(2) O^(-), (CH_3)_3 N, CI^(+), CH_3 C^(+) = O, H_(2) N^(-) :, NO_(2)^(+)

Giving proper justification categorise the following molecules/ions as nucleophile or electrophile : HS^(-), BF_(3), C_(2)H_(5)O^(-), (CH_(3))_(3)N, Cl^(+), CH_(3)overset(+)(C) = O, H_(2)N:^(-), overset(+)(N)O_(2) .

Knowledge Check

  • Which among the following compound behave both as an electrophile as well as nucleophile (a) CH_(2) - CH_(2) (b) CH_(2) = CH - CH_(2) (c ) CH_(3) - oversetoverset(O)("||")C-CH_(3) (d) CH_(3) - oversetoverset(O)("||")C-Cl

    A
    Only a
    B
    a and b
    C
    c and d
    D
    b,c and d
  • Which among the following compounds behaves both as an electrophile as well as a nucleophile? (1) CH_2=CH_2 , (2) RCOCl , (3) CH_3-oversetOoverset"||"C-CH_3 , (4)R-O-R

    A
    Only 1
    B
    1 and 2
    C
    3 and 4
    D
    2,3 and 4
  • Which of the following species is/are isoelectronic to each other ? (I) overset(Θ)(B)H_(3) - C -= N (II) CH_(3) - C -= CH (III) N_(2)O

    A
    I and II only
    B
    II and III only
    C
    I, II and III only
    D
    All four
  • Similar Questions

    Explore conceptually related problems

    Which of the following in each pair has larger bond angle (i) CO_(2) , BF_(3) (ii) H_(2)O, H_(2)S (iii) CH_(4), C_(2)H_(2)

    Arrange the following species in order of decreasing nucleophilicity in a polar protic solvent. (I). CH_(3)CH_(2)CH_(2)O^(-) , (II). CH_(3)CH_(2)CH_(2)S^(-) (III). CH_(3)-CH_(2)-overset(O)overset(||)(C)-overline(O)

    Which of the following were called permanent gases ? (i) H_(2) , (ii) O_(2) (iii) N_(2) , (iv) CH_(4)

    Which of the following is not nucleophiles? (i) HCl (ii) SiF_(4) (iii) P(CH_(3))_(3) (iv) CH_(2)=CH_(2)

    Which of the following undergoes haloform reaction? (i) CH_(3)CH_(2)COCH_(2)CI (ii) C_(6)H_(5)COCH_(3) (iii) C_(6)H_(5)COCHI_(2) (iv) CH_(3)CH_(2)COCCI_(3)