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The hydrocarbon which can react with sod...

The hydrocarbon which can react with sodium in liquid ammonia is

A

`CH_3CH_2C-=C CH_2CH_3`

B

`CH_3CH_2CH_2C-=C CH_2CH_2CH_3`

C

`CH_3CH_2C-=CH`

D

`CH_3CH=CHCH_3`

Text Solution

Verified by Experts

The correct Answer is:
C


Sodium in liquid ammonia provides the amide ion able to remove the acetylenic protons of terminal alkynes `(pk_a=25)`
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Knowledge Check

  • Which of the hydrocarbons is reduced by sodium and liquid ammonia?

    A
    `CH_3CH_2C-=CH`
    B
    `CH_3C-=CH_3`
    C
    `CH_3CH=CHCH_3`
    D
    `CH_3CH_2CH=CH_2`
  • But-2-yne on reaction with sodium in liquid ammonia produces

    A
    butyne
    B
    trans-2-butene
    C
    cis-2-butene
    D
    no reaction
  • Alkynes on reduction with sodium in liquid ammonia forms

    A
    cis alkene
    B
    cis alkane
    C
    trans alkene
    D
    trans alkane
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