Home
Class 12
CHEMISTRY
The Compounds [Cr(H(2)O)(6)]CI(3) , [Cr(...

The Compounds `[Cr(H_(2)O)_(6)]CI_(3)` , `[Cr(H_(2)O)_(5)CI]CI_(2)` . `H_(2)O` and `[Cr(H_(2)O)_(4)CI_(2)]` . `2H_(2)O` exhibit

A

hydrate isomerism

B

ionization isomerism

C

linkage isomerism

D

coordination isomerism

Text Solution

Verified by Experts

The correct Answer is:
A
Hydrate isomerism is a special form of ionization isomerism. It occurs when water forms a part of the coordination entity or is outside it. Thus in hydrate isomers, water can be inside and outside the coordination sphere.
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • COORDINATION COMPOUNDS

    R SHARMA|Exercise Question Bank (Building the knowledge)|38 Videos

  • COORDINATION COMPOUNDS

    R SHARMA|Exercise Archives|56 Videos

  • CHEMISTRY IN EVERYDAY LIFE

    R SHARMA|Exercise Archives|11 Videos

  • ELECTROCHEMISTRY

    R SHARMA|Exercise Follow-up Test 11|7 Videos

Similar Questions

Explore conceptually related problems

coordination compounds often show various types of isomerism. The isomerism can be categorized in two main types (a) structural isomerism (b) stereo or space isomerism Structural isomerism arises due to the difference in structures of coordination-sempounds while stereo or space isomerism arises on account of the different positions and arrangements of ligands (atoms or groups) in space around the metal lonStructural isomerism can be classified in following types (i) tonization isomers- which give different ions in solution, e.g. [CoBr(NH_(3))_(5)]]SO_(4) and [Co(SO_(4))_(5)(NH_(3))_(5)]Br Hydrate isomers which differ in H_(2)O as ligand or as hydration, e.g. [Cr(H_(2)O)_(5)]CI_(2)(H_(2)O)]Cl_(2).H_(2)O[CrCl_(2)(H_(2)O)]CI.2H_(2)O (iii) Linkage isomers, which differ in atom linked to 'metal atom, e.g. [CO(NO_(2))(NH_(3))_(5)]^(2+) and CO(ONO)(NH_(3))_(6)]^(2+) Coordination isomers- which involve interchange of ligands, e.g. [Co(NH_(3))_(6)] [Cr(CN)_(6)] and [Cr(NH_(3))_(6)] [Co(CN)_(6)] (v) Coordination position isomerism-which arises in the bridged complexes due to the difference in the attachment of ligands with the metal atoms QThe compounds [Cr(H_(2)O_(6))Cl_(3)[Cr(H_(2)O)_(5)CI]Cl_(2).H_(2)O and [Cr(H_(2)O)_(4),CI_(2)]CI2H_(2)O exhibit

coordination compounds often show various types of isomerism. The isomerism can be categorized in two main types (a) structural isomerism (b) stereo or space isomerism Structural isomerism arises due to the difference in structures of coordination-sempounds while stereo or space isomerism arises on account of the different positions and arrangements of ligands (atoms or groups) in space around the metal lonStructural isomerism can be classified in following types (i) tonization isomers- which give different ions in solution, e.g. [CoBr(NH_(3))_(5)]]SO_(4) and [Co(SO_(4))_(5)(NH_(3))_(5)]Br Hydrate isomers which differ in H_(2)O as ligand or as hydration, e.g. [Cr(H_(2)O)_(5)]CI_(2)(H_(2)O)]Cl_(2).H_(2)O[CrCl_(2)(H_(2)O)]CI.2H_(2)O (iii) Linkage isomers, which differ in atom linked to 'metal atom, e.g. [CO(NO_(2))(NH_(3))_(5)]^(2+) and CO(ONO)(NH_(3))_(6)]^(2+) Coordination isomers- which involve interchange of ligands, e.g. [Co(NH_(3))_(6)] [Cr(CN)_(6)] and [Cr(NH_(3))_(6)] [Co(CN)_(6)] (v) Coordination position isomerism-which arises in the bridged complexes due to the difference in the attachment of ligands with the metal atoms QThe compounds [Cr(H_(2)O_(6))Cl_(3)[Cr(H_(2)O)_(5)CI]Cl_(2).H_(2)O and [Cr(H_(2)O)_(4),CI_(2)]CI2H_(2)O exhibit

Knowledge Check

  • The compounds [Cr(H_(2)O)_(6)]Cl_(3),[Cr(H_(2)O)_(5)Cl]Cl_(2)H_(2)O and [Cr(H_(2)O)_(4)Cl_(2)]Cl*2H_(2)O exhibits:

    A
    linkage isomerism
    B
    geometrical isomerism
    C
    ionization isomerism
    D
    hydrate isomerism

  • The compounds [Cr(H_(2)O)_(6)]Cl_(3) and [Cr(H_(2)O)_(4) Cl_(2)]Cl.2H_(2)O represent

    A
    Linkage isomerism
    B
    Hydrate isomerism
    C
    Ligand isomerism
    D
    None of these

  • The compounds [Cr(H_(2)O)_(6)]Cl_(3) and [Cr(H_(2)O)5C_(1)]Cl_(2)*H_(2)O are examples of

    A
    Linkage isomerism
    B
    Hydrate isomerism
    C
    Ionisation isomerism
    D
    Co-ordination isomerism

    • Similar Questions

    Explore conceptually related problems

    The pair [Cr(H_(2)O)_(6)]CI_(3) and [Cr(H_(2)O)_(4)CI_(2)]CI.H_(2)O shows ionisation isomerism .

    The ionisation isomer of [Co(H_(2)O)_(4)CI_(2)NO (a) [Co(H_(2)O)_(4)(NO_(2))]CI_(2) (b) [Co(H_(2)O)_(4)CI_(2)]NO_(2) [Co(H_(2)O)_(4)CI(ONO)]CI (d ) [Co(H_(2)O)_(4)CI_(2)(NO_(2))]H_(2)O .

    The complex [Cr(H_(2)O)_(5)Cl]Br and [Cr(H_(2)O)_(5)Br]Cl show

    The pair of complex compounds [Cr(H_(2)O)_(6)]Cl_(3) and [Cr(H_(2)O)_(5)Cl]Cl_(2)H_(2)O are an example of

    Which type of isomerism is shown by [Cr(H_(2)O)_(6)]Cl_(3) and [Cr(H_(2)O)_(5)Cl]Cl_(2).H_(2)O ?

    Home
    Profile