Home
Class 12
CHEMISTRY
What is the shape of Fe(CO)(5) molecule ...

What is the shape of `Fe(CO)_(5)` molecule ? Given that its dipole moment = 0.

A

octahedral

B

square planar

C

trigonal bipyramidal

D

square bipyramidal

Text Solution

Verified by Experts

The correct Answer is:
C

In `[Fe(CO)_(5)]` the oxidation number of Fe is zero `Fe^(0) (3d^(6) 4d^(2))` Since CO is a strong field ligand, the electron configuration is resuffled so as to provide one vacant d orbital for `dsp^(3)` hybrization leaging to trigonal bipyramidal geometry as well as shape.
Promotional Banner

Topper's Solved these Questions

  • COORDINATION COMPOUNDS

    R SHARMA|Exercise Question Bank (Building the knowledge)|38 Videos
  • CHEMISTRY IN EVERYDAY LIFE

    R SHARMA|Exercise Archives|11 Videos
  • ELECTROCHEMISTRY

    R SHARMA|Exercise Follow-up Test 11|7 Videos

Similar Questions

Explore conceptually related problems

The molecule that will have dipole moment is:

The molecule which have zero dipole moments is .

The molecule which has zero dipole moment is

The molecule which has zero dipole moment is

The molecule having zero dipole moment is

The molecule having permanent dipole moment is

R SHARMA-COORDINATION COMPOUNDS-Archives
  1. Considering H2O as a weak field ligand, the number of unpaired electro...

    Text Solution

    |

  2. CN^(-) is a strong field ligand. This is due to the fact that

    Text Solution

    |

  3. Which of the following does not have a metal carbon bond?

    Text Solution

    |

  4. Which of the following is considered to be an anticancer species ?

    Text Solution

    |

  5. Which of the following coordination compounds would exhibit optical is...

    Text Solution

    |

  6. Among the following, which is not the pi - bonded organometallic compo...

    Text Solution

    |

  7. The number of unpaired electrons in the complex ion [CoF6]^(3-) is (At...

    Text Solution

    |

  8. According to IUPAC nomenclature sodium nitroprusside is named as

    Text Solution

    |

  9. Which of the following octahedral complex does not show geometrical is...

    Text Solution

    |

  10. The hypothetical complex triamminediaquachloridocobalt(III) chloride c...

    Text Solution

    |

  11. Atomic numbers of Cr and Fe are respectively 24 and 26. Which of the f...

    Text Solution

    |

  12. In the silver plating of copper, K[Ag(CN)(2)] is used instead of AgNO(...

    Text Solution

    |

  13. Which of the following will give maximum number of isomer ?

    Text Solution

    |

  14. Which of the following organometallic compound is sigma and pi-bonded?

    Text Solution

    |

  15. Coordination number of Ni in [Ni(C2O4)3]^(4-) is:

    Text Solution

    |

  16. Which statement is incorrect?

    Text Solution

    |

  17. Which of the following will exhibit maximum ionic conductivity ?

    Text Solution

    |

  18. Which of the following complexes will have four isomers ?

    Text Solution

    |

  19. In the separation of Cu^(2+) and Cd^(2+) of Iind group in qualitative ...

    Text Solution

    |

  20. What is the shape of Fe(CO)(5) molecule ? Given that its dipole moment...

    Text Solution

    |