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Enantiomers have identical...

Enantiomers have identical

A

medicinal (drug) properties

B

smells

C

tastes

D

melting points

Text Solution

Verified by Experts

The correct Answer is:
D

Enantiomers have identical physical and chemical properties under achiral conditions. In other words, enantiomers show different properties (physical as well as chemical) only in a chiral medium. Enantiomers differ in direction of the rotation of the plane polarized light (a physical property) beacuse polarized light provides a chiral medium. Enantiomers also differ in solubility in an optically active solvent and in adsorption on an optically active surface. For enantiomers to react at different rates, the necessary chiral medium can be provided in a number of ways: by an optically acitve regent, by a chiral solvent or the chiral surface of a catalyst and by irradiation with circularly polarized light (for light-catalyed reacrions). For simplicity, we often use the term ''optically active reacgent'' or ''chiral reagent'' in specking of reaction under an of these chiral conditions. On the other hand, we use the term ''optically inactive reagent'' or ''achirakl reagen'' or even ''ordinary conditions'' in specking of reaction in the absence of a chiral medium.
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Knowledge Check

  • Enantiomers are

    A
    molecule that have at least one chiral carbon
    B
    non-superimposible molecules that are mirror images of one another
    C
    non-superimposible constitutional isomers
    D
    non-superimposible molecules
  • The (R-) and (S-) enantiomers of an optically active compound differ in

    A
    their reactivity with achiral reagents
    B
    their optical rotation of plane polarized light
    C
    their melting points
    D
    None of these
  • The (R ) and (S) enantiomers of an optically active compound differ in

    A
    Their reactivity with achiral reagents
    B
    Their optical rotation of plane polarized light
    C
    Their melting points
    D
    Their solubility in archiral reagents
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