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A compound (X) with the molecular formul...

A compound `(X)` with the molecular formula `C_(3)H_(8)O` can be oxidized to another `(Y)` whose molecular formula is `C_(6)H_(6)O_(2)`
The compound `(X)` may be

A

`CH_(3)CHOHCH_(3)`

B

`CH_(3)CH_(2)CH_(2)OH`

C

`CH_(3)CH_(2)OCH_(3)`

D

`CH_(3)CH_(2)CHO`

Text Solution

Verified by Experts

The correct Answer is:
B

`underset((X)) underset(C_(n)H_(2n + 2)O)(C_(3))H_(8)O overset([O])rarr underset((Y))underset(C_(n)H_(2n)O_(2))(C_(3)H_(6)O_(2))`
The general formula `C_(n)H_(2n + 2)O` Corresponds to monohydric alcohols as well as ethers. Ethers are not easily oxidized.
`2^(@)` alcohols are oxidized to ketones and then to a mixture of acids each having fewer carbon atoms than the corresponding alcohol . Thus , `(X)` must be primary alcohol.
`CH_(3)underset((X))(CH_(2)CH_(2)OH) overset([O]) rarr CH_(3)underset((Y))(COOH)`
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Knowledge Check

  • A compound X with moleuclar formula C_(3)H_(8)O can be oxidized to a compoud Y with the molecular formula C_(3)H_(6)O_(2) . X is most likely to be a:

    A
    primary alcohol
    B
    secondary alcohol
    C
    aldehyde
    D
    ketone
  • A compound X with molecular formula C_3H_8O can be oxidised to a compound Y with the molecular formula C_3H_6O_2 . The compound X is most likely to be

    A
    Primary alcohol
    B
    secondary alcohol
    C
    Aldehyde
    D
    ketone
  • A compound X with molecular formula C_(3)H_(8)O can be oxidised to a compound Y with the moleculr formula C_(3)H_(6)O_(2) , X is most likely to be -

    A
    Primary alcohol
    B
    Secondary alcohol
    C
    Aldehyde
    D
    Ketone
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