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Ethanol has higher boiling point than et...

Ethanol has higher boiling point than ethanol because

A

ethanol is a polar compound but ethanol is not

B

ethanol forms intermolecular hydrogen bond but ethanal does not

C

ethanol has higher molecular mass than ethanol

D

ethanol forms stronger intermolecular hydrogen bonds than does ethanol

Text Solution

Verified by Experts

The correct Answer is:
B

Both ethanol and ethanol are polar compounds and have comparable molecular masses . The high melting point of ethanol is mainly due to the presence of intermolecular hydrogen bonding between its molecules which is lacking in ethanol.
`C_(2)H_(5)-overset(delta-)ddotunderset(H)underset(|)(O)overset(.).---overset(delta+)(H)-overset(C_(2)H_(5))underset(delta+)underset(..)(O)overset(.)(.)---overset(delta+)(H)---overset(delta-)ddotunderset(C_(2)H_(5))underset(|)(O)overset(.)(.)---`
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Knowledge Check

  • Statement-I: Chloropropane has higher boiling point than chloroethane. Because Statement-II: Haloalkanes are polar molecules.

    A
    Statement-I is True, Statement-II is True, Statement-II is a correct explanation for Statement-I
    B
    Statement-I is True, Statement-II is True, Statement-II is NOT a correct explanation for Statement-I
    C
    Statement-I is True, Statement-II is False.
    D
    Statement-I is False, Statement-II is True.
  • NH_(3) has higher boiling point than expected because

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    It froms `NH_(4)OH ` with water
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    It has intramolecular hydrogen bonds
    C
    It has intramolecular hydrogen bonds
    D
    Its density decreases bond on freezing
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