Home
Class 12
CHEMISTRY
When phenol reacts with phosphorus penta...

When phenol reacts with phosphorus pentachloride, the main product is

A

`C_(6)H_(5)Cl`

B

`(C_(6)H_(5))_(3)PO_(4)`

C

`(C_(6)H_(5))_(3)PO_(3)`

D

`C_(6)Cl_(6)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the main product when phenol reacts with phosphorus pentachloride (PCl5), we can follow these steps: ### Step 1: Understand the Reactants - **Phenol (C6H5OH)** is an aromatic compound with a hydroxyl (-OH) group attached to a benzene ring. - **Phosphorus pentachloride (PCl5)** is a chlorinating agent that can react with alcohols and phenols. ### Step 2: Identify the Reaction When phenol reacts with phosphorus pentachloride, the hydroxyl group (-OH) of phenol can be replaced by a chlorine atom. However, PCl5 can also lead to the formation of more complex products. ### Step 3: Determine the Products 1. **Chlorobenzene (C6H5Cl)**: This is formed when the hydroxyl group of phenol is replaced by a chlorine atom. However, this is not the major product. 2. **Triphenyl Phosphate (C18H15O4P)**: This is the major product formed when phenol reacts with PCl5. In this reaction, three phenol molecules react with one molecule of PCl5 to form triphenyl phosphate and phosphorus oxychloride (POCl3). ### Step 4: Write the Reaction Equation The overall reaction can be summarized as: \[ 3 C6H5OH + PCl5 \rightarrow C18H15O4P + 3 HCl \] ### Conclusion The main product of the reaction between phenol and phosphorus pentachloride is **triphenyl phosphate (C18H15O4P)**. ---

To determine the main product when phenol reacts with phosphorus pentachloride (PCl5), we can follow these steps: ### Step 1: Understand the Reactants - **Phenol (C6H5OH)** is an aromatic compound with a hydroxyl (-OH) group attached to a benzene ring. - **Phosphorus pentachloride (PCl5)** is a chlorinating agent that can react with alcohols and phenols. ### Step 2: Identify the Reaction When phenol reacts with phosphorus pentachloride, the hydroxyl group (-OH) of phenol can be replaced by a chlorine atom. However, PCl5 can also lead to the formation of more complex products. ...
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • ALCOHOL, PHENOL AND ETHERS

    R SHARMA|Exercise Follow -Up Test -11|17 Videos
  • ALCOHOL, PHENOL AND ETHERS

    R SHARMA|Exercise Follow -Up Test -12|14 Videos
  • ALCOHOL, PHENOL AND ETHERS

    R SHARMA|Exercise Follow -Up Test -9|5 Videos
  • AMINES

    R SHARMA|Exercise Archives|36 Videos

Similar Questions

Explore conceptually related problems

Propanone when react with phosphorus pentachloride it gives-

Phosphorus pentachloride in the solid exists as :

Knowledge Check

  • Acetone reacts with phosphorous pentachloride to give:

    A
    Vic-dihalide
    B
    `alpha, alpha` -dihalide
    C
    Gem-dihalide
    D
    `alpha, omega`- dihalide
  • Phosphorus pentachloride is ionic in

    A
    vapour state
    B
    liquid state
    C
    solid state
    D
    all the three states
  • Na reacts with phenol

    A
    `H_(2)` gas
    B
    Benzene
    C
    `CO_(2)` gas
    D
    CO gas
  • Similar Questions

    Explore conceptually related problems

    When ethyl bromide reacts with sodium acetylide the main product is

    When phenol reacts with benzene diazonium chloride, the product obtained is

    When phenol reacts with benzene diazonium chloride , the product obtained is :

    When benzamide is heated with phosphorus pentoxide, the product formed is:

    Acetaldoxirne reacts with phosphorus pentoxide to give: