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For a zero order reaction of the type A ...

For a zero order reaction of the type `A rarr` products, the integrated rate equation may be expressed as

A

`k = ([A]_(0)-[A])/(2).t`

B

`k = ([A]_(0)-[A])/(2t)`

C

`k = ([A]-[A]_(0))/(t)`

D

`k = ([A]_(0)-[A])/(t)`

Text Solution

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The correct Answer is:
To derive the integrated rate equation for a zero-order reaction of the type \( A \rightarrow \text{products} \), we can follow these steps: ### Step 1: Understand the zero-order reaction In a zero-order reaction, the rate of reaction is constant and does not depend on the concentration of the reactant \( A \). The rate law for a zero-order reaction can be expressed as: \[ \text{Rate} = k \] where \( k \) is the rate constant. ### Step 2: Relate rate to concentration The rate of change of concentration of \( A \) can be expressed as: \[ -\frac{d[A]}{dt} = k \] This indicates that the concentration of \( A \) decreases at a constant rate \( k \). ### Step 3: Integrate the rate equation To find the integrated form, we can rearrange the equation and integrate: \[ d[A] = -k \, dt \] Integrating both sides gives: \[ \int [A]_0^{[A]} d[A] = -k \int_0^t dt \] This results in: \[ [A] - [A]_0 = -kt \] where \([A]_0\) is the initial concentration of \( A \). ### Step 4: Rearranging the equation Rearranging the equation gives us the integrated rate equation for a zero-order reaction: \[ [A] = [A]_0 - kt \] ### Final Answer The integrated rate equation for a zero-order reaction of the type \( A \rightarrow \text{products} \) is: \[ [A] = [A]_0 - kt \] ---

To derive the integrated rate equation for a zero-order reaction of the type \( A \rightarrow \text{products} \), we can follow these steps: ### Step 1: Understand the zero-order reaction In a zero-order reaction, the rate of reaction is constant and does not depend on the concentration of the reactant \( A \). The rate law for a zero-order reaction can be expressed as: \[ \text{Rate} = k \] where \( k \) is the rate constant. ...
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Knowledge Check

  • The first order integrated rate equation is

    A
    `k = (x)/(t)`
    B
    `k = - ""(2.303)/(t) "log" (a)/(a-x)`
    C
    `k = (1)/(t) "ln" (a)/(a-x)`
    D
    `k =(1)/(t) (x)/(a(a-x))`
  • For a zero order reaction, the integrated rate equation is

    A
    `kt=([A])/([A]_(0))`
    B
    `kt=[A]-[A]`
    C
    `[A]=-kt+[A]_(0)`
    D
    `[A]=kt-[A]_(0)`
  • For a gaseous reaction, the rate of reaction may be expressed in the units

    A
    atm
    B
    atm s
    C
    atm/s
    D
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