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When hybridisation involving d-orbitals ...

When hybridisation involving d-orbitals are considered then all the five d-orbitals are not degenerate, rather `d_(x^(2)-y^(2)),d_(s^(2)) and d_(xy),d_(zx)` form two different sets of orbitals and orbitals of appropriate set is involved in the hybridisation.
In `sp^(3)d^(2)` hybridisation, which sets of d-orbitals is involved ?

A

`d_(x^(2)-y^(2)),d_(z^(2))`

B

`d_(z^(2)),d_(xy)`

C

`d_(xy),d_(yz)`

D

`d_(x^(2)-y^(2)),d_(xy)`

Text Solution

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The correct Answer is:
A
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When hybridisation involving d-orbitals are considered then all the five d-orbitals are not degenerate, rather d_(x^(2)-y^(2)),d_(s^(2)) and d_(xy),d_(zx) form two different sets of orbitals and orbitals of appropriate set is involved in the hybridisation. Which of the following orbitals can not undergo hybridisation amongst themselves. (I) 3d,4s " " (II) 3d,4d (III) 3d,4s & 4p " " (IV) 3s,3p & 4s

Knowledge Check

  • When hybridisation involving d-orbitals are considered then all the five d-orbitals are not degenerate, rather d_(x^(2)-y^(2)),d_(s^(2)) and d_(xy),d_(zx) form two different sets of orbitals and orbitals of appropriate set is involved in the hybridisation. In sp^(3)d^(3) hybridisation, which orbitals are involved ?

    A
    `d_(x^(2)-y^(2)),d_(z^(2)),d_(xy)`
    B
    `d_(xy),d_(yz),d_(zx)`
    C
    `d_(x^(2)-y^(2)),d_(xy),d_(xz)`
    D
    `d_(x^(2)),d_(yz),d_(zx)`

  • When hybridisation involving d-orbitals are considered then all the five d-orbitals are not degenerate, rather d_(x^(2)-y^(2)),d_(s^(2)) and d_(xy),d_(zx) form two different sets of orbitals and orbitals of appropriate set is involved in the hybridisation. Molecule having trigonal bipyramidal geometry and sp^(3) d hybridisation, d-orbitals involved is :

    A
    `d_(xy)`
    B
    `d_(yz)`
    C
    `d_(x^(2)-y^(2))`
    D
    `d_(z^(2))`

  • When hybridisation involving d-orbitals are considered then all the five d-orbitals are not degenerate, rather d_(x^(2)-y^(2)),d_(s^(2)) and d_(xy),d_(zx) form two different sets of orbitals and orbitals of appropriate set is involved in the hybridisation. Molecule having trigonal bipyramidal geometry and sp^(3) d hybridisation, d-orbitals involved is :

    A
    `d_(xy)`
    B
    `d_(yz)`
    C
    `d_(x^(2)-y^(2))`
    D
    `d_(z^(2))`

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    When hybridisation involving d-orbitals are considered then all the five d-orbitals are not degenerate, rather d_(x^(2)-y^(2)),d_(s^(2)) and d_(xy),d_(zx) form two different sets of orbitals and orbitals of appropriate set is involved in the hybridisation. Which of the following orbitals can not undergo hybridisation amongst themselves. (I) 3d,4s " " (II) 3d,4d (III) 3d,4s & 4p " " (IV) 3s,3p & 4s

    The d-orbitals involved in dsp^2 hybridisation is

    d^(2)sp(3) hybridisation of the atomic orbital gives :

    The d-orbital involved in sp^3d hybridisation is

    The d-orbitals involved in sp^(3)d hybridisation is:

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