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Hybridisation involves the mixing of orb...

Hybridisation involves the mixing of orbitals having comparable energhies of same atom. Hybridised orbitals perform efficient overlapping than overlapping by pure s, p or orbitals.
Which of the following is not correctly match between given species and type of overlapping ?

A

`XeO_(3)` : Three `(d pi - p pi)` bonds

B

`H_(2)SO_(4)` : Two `(d pi - p pi)` bonds

C

`SO_(3)` : Three `(d pi - p pi)` bonds

D

`HClO_(4)` : Three `(d pi - p pi)` bonds

Text Solution

Verified by Experts

The correct Answer is:
C

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Knowledge Check

  • Hybridisation involves the mixing of orbitals having comparable energhies of same atom. Hybridised orbitals perform efficient overlapping than overlapping by pure s, p or orbitals. Consider the following compounds and select the incorrect statement from the following : NH_(3),PH_(3),H_(2)S,SO_(2),BF_(3),PCl_(3),IF_(7),P_(4),H_(2)

    A
    Six molecules out of given compounds involves hybridisation
    B
    Three molecules are hypervalent compounds
    C
    Six molecules out of above compounds are non-planar in structure
    D
    Two molecules out of given compounds involves `(d pi- p pi)` bonding as well as also involves `( p pi- p pi)` bonding
  • Which of the following orbitals will not form sigma bond after overlapping ?

    A
    s - orbital and s- orbital
    B
    s- orbital and `p_(z) -` orbital
    C
    `p_(z)`- orbital and `p_(z)-` orbital
    D
    `p_(x)`-orbital and `p_(x)`- orbital
  • Which of the following orbitals of a diatomic molecule AB will not have positive overlap ?

    A
    2s(A) and 2s(B)
    B
    2s(A) and `2P_z(B)`
    C
    `2P_z(A) and 2P_z(B)`
    D
    `2P_x(A) and 2P_z(B)`
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    Hyperconjugation involves overlap of which of the following orbitals?

    Hybridisation is the mixing of atomic orbital of comparable energy and the number of hybrid orbitals formed is equal to the number of pure atomic orbitals mixed up and hybrid orbitals are occupied by sigma -bond pair and lone pair. ''The hybrid orbitals are at at angle of X^(@) to one another''. This statement is not valid for which of the following hybridisation?