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Consider the following two reactions: ...

Consider the following two reactions:
`Cd^(2+)(aq.)+4CH_(3)NH_(2) overset(K_(1)) to 'A',DeltaG_(1)^(@)`
`Cd^(2+)(aq.)+2H_(2)NCH_(2)CH_(2)NH_(2) overset(K_(2)) to 'B',DeltaG_(2)^(@)`. According to given information the correct statement(s) is/are:

A

`DeltaG_(2)^(@)` is more negative than `DeltaG_(1)^(@)`

B

Compound 'A" is optically inactive

C

Compound 'B' is optically active

D

Formation constant `K_(2)` is greater than formation constant `K_(1)`

Text Solution

Verified by Experts

The correct Answer is:
A, B, D
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Knowledge Check

  • Consider the following two reactions: Cd^(2+)(aq.)+4CH_(3)NH_(2) overset(K_(1)) ot 'A",DeltaG_(1)^(@) Cd^(2+)(aq.)+2H_(2)NCH_(2)CH_(2)NH_(2) overset(K_(2)) to 'B',DeltaG_(2)^(@) According to given information the correct statement(s) is/are:

    A
    `DeltaG_(2)^(@)` is more negative than `DeltaG_(1)^(@)`
    B
    Compound 'A" is optically inactive
    C
    Compound 'B' is optically active
    D
    Formation constant `K_(2)` is greater than formation constant `K_(1)`

  • Consider the following reaction CH_(3)- CONH_(2) overset(I)to CH_(3)-NH_(2) overset(II) to CH_(3)NC

    A
    Reaction I is called Hofmann's amine reaction
    B
    Reaction II is called carbyl amine reaction
    C
    Reaction I and II are Hofmann reactions
    D
    Both 'a' and 'b' are correct statements.

  • Product of the following reaction is CH_(3) - CH_(4)-CH_(2) - NO_(2) overset(Zn + NH_(4)Cl) to ?

    A
    B
    C
    D

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