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Consider the following compounds with th...

Consider the following compounds with their regular geometries.

Calculate value of `(x+y-z)^(2)`, where x is total number of axial d-orbitals having zero nodal plane, y and z are total no. of non-axial and axial d-orbitals respectively each one having two nodal planes used in hybridisation of central atoms of compounds A to E.

Text Solution

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The correct Answer is:
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`x=d_(x^(2))=3`
`y=d_(xy)=1,(x+y-z)^(2)=(3+1-4)^(2)=0`
`z=d_(x^(2)-y^(2))+4`
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Knowledge Check

  • In which of the following species, d-obitals having xz an yz two nodal planes involved in hybridization of central atoms?

    A
    `IO_(2)F_(2)^(-)`
    B
    `ClF_(4)^(-)`
    C
    `IF_(7)`
    D
    None of these

  • In which of the following species, d-obitals having xz an yz two nodal planes involved in hybridization of central atoms?

    A
    `IO_(2)F_(2)^(-)`
    B
    `ClF_(4)^(-)`
    C
    `IF_(7)`
    D
    None of these

  • In which of the following species d -orbitals having xz and yz two nodel planes involved in hyridisation of central atom?

    A
    `IO_(2)F_(2)^(ө)`
    B
    `SF_(6)`
    C
    `IF_(7)`
    D
    None

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