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CO(g)+H(2)(g)overset(Cu)toX CO(g)+H(2)...

`CO(g)+H_(2)(g)overset(Cu)toX`
`CO(g)+H_(2)(g)overset(Cu//ZnO-Cr_(2)O_(3))toY`
`CO(g)+H_(2)(g)overset(Ni)toZ`
X,Y and Z respectively are

A

`CH_(3) OH, HCHO, CH_(4)`

B

`HCHO, CH_(3)OH, CH_(4)`

C

`CH_(4), CH_(3)OH,k CH_(4)`

D

`CHOH, CH_(4),CH_(3)OH`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to identify the products (X, Y, and Z) formed from the reactions of carbon monoxide (CO) and hydrogen gas (H2) in the presence of different catalysts. ### Step-by-step Solution: 1. **Identify the reaction with Copper (Cu):** - The reaction is: \[ CO(g) + H_2(g) \overset{Cu}{\rightarrow} X \] - In the presence of copper, CO reacts with H2 to form formaldehyde (HCHO). - Therefore, \( X = HCHO \). 2. **Identify the reaction with Copper, Zinc Oxide, and Chromium Oxide (Cu/ZnO-Cr2O3):** - The reaction is: \[ CO(g) + H_2(g) \overset{Cu/ZnO-Cr_2O_3}{\rightarrow} Y \] - In this case, the presence of Cu with ZnO and Cr2O3 facilitates the conversion of CO and H2 to methanol (CH3OH). - Therefore, \( Y = CH_3OH \). 3. **Identify the reaction with Nickel (Ni):** - The reaction is: \[ CO(g) + H_2(g) \overset{Ni}{\rightarrow} Z \] - In the presence of nickel, CO reacts with H2 to produce methane (CH4). - Therefore, \( Z = CH_4 \). ### Summary of Products: - \( X = HCHO \) (Formaldehyde) - \( Y = CH_3OH \) (Methanol) - \( Z = CH_4 \) (Methane) ### Final Answer: The products X, Y, and Z respectively are: - X = HCHO - Y = CH3OH - Z = CH4

To solve the question, we need to identify the products (X, Y, and Z) formed from the reactions of carbon monoxide (CO) and hydrogen gas (H2) in the presence of different catalysts. ### Step-by-step Solution: 1. **Identify the reaction with Copper (Cu):** - The reaction is: \[ CO(g) + H_2(g) \overset{Cu}{\rightarrow} X ...
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How many of these reactions are homogeneously catalyzed ? (i) 2SO_(2)(g) + O_(2)(g) overset(NO(g))to 2SO_(3)(g) (ii) C_(12)H_(22)O_(11)(aq.) + H_(2)O(l) overset(H_(2)SO_(4)(l))to underset("Glucose")(C_(6)H_(12)O_(6)(aq.)) + underset("Fructose")(C_(6)H_(12)O_(6)(aq.)) (iii) 2SO_(3)(g) + O_(2)(g) overset(Pt(s))to 2SO_(3)(g) (iv) N_(2)(g) + 3H_(2)(g) overset(Fe(s))to 2NH_(3)(g) (v) 4NH_(3)(g) + 5O_(2)(g) overset(Pt(s))to 4NO(g) + 6H_(2)O(g) (vi) CH_(3)COOCH_(3)(l) overset(HCl(l))to CH_(3)COOH(aq) (vii) Vegetable oils (l) + H_(2)(g)overset(Ni(s))to Vegetable ghee (s).

Calculate Delta_(f)H^(@) for the reaction, CO_(2)(g) + H_(2)(g) to CO(g) + H_(2)O(g) Given that Delta_(f)H^(@) for CO_(2)(g) , CO(g) and H_(2)O(g) are -393.5, -111.3 and -241.8 kJ mol^(-1) respectively.

Knowledge Check

  • Which of the following feature of catalysts is described in reactions given below? (i) CO(g) +2H_(2)(g) overset(Cu//ZnO-Cr_(2)O_(3))rarr CH_(3)OH (g) (ii) CO(g) +H_(2) (g) overset(Cu)rarr HCHO (g) (iii) CO(g) +3H_(2)(g) overset(Ni)rarr CH_(4)(g) +H_(2)O(g)

    A
    Activity
    B
    Selectivity
    C
    Catalytic promoter
    D
    Catalytic poison
  • 2H_2O (l) overset(Delta)to 2H_2(g) + O_2(g) is -

    A
    Combination reaction
    B
    Decomposition reaction
    C
    Displacement reaction
    D
    None of these
  • The heat energy required to ionise the following molecules is given as follows N_(2)(g) overset(DeltaH_(1))to H_(2)^(o+)(g),O_(2)(g) overset(DeltaH_(2))to O_(2)^(+)(g) Li_(2)(g) overset(DeltaH_(3)) to Li_(2)^(o+)(g),C_(2)(g) overset(DeltaH_(4))to C_(2)^(o+)(g) The correct decreasing order of energy in terms of heat

    A
    `DeltaH_(1) gt DeltaH_(3) gt DeltaH_(2) gt DeltaH_(4)`
    B
    `DeltaH_(2) gt DeltaH_(3) gt DeltaH_(1) gt DeltaH_(4)`
    C
    `DeltaH_(3) gt DeltaH_(4)gt DeltaH_(1) gt DeltaH_(2)`
    D
    `DeltaH_(3) gt DeltaH_(1) gt DeltaH_(4) gt DeltaH_(2)`
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