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Above 1073 K, ………… reduces FeO to Fe...

Above 1073 K, ………… reduces FeO to Fe while below 1073K, …………… reduces ` Fe_ 2 O _ 3 ` to Fe.

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To solve the question, we need to identify the reducing agents used for the reduction of FeO to Fe and Fe2O3 to Fe at different temperatures. ### Step-by-Step Solution: 1. **Understanding the Reduction Process**: - Reduction is a chemical reaction that involves the gain of electrons or the removal of oxygen from a substance. In this case, we are reducing iron oxides (FeO and Fe2O3) to iron (Fe). 2. **Identifying the Temperature Condition**: - The question specifies two temperature conditions: above 1073 K and below 1073 K. 3. **Reduction of FeO Above 1073 K**: - At temperatures above 1073 K, coke (carbon) is typically used as a reducing agent. The reaction can be represented as: \[ \text{FeO} + \text{C} \rightarrow \text{Fe} + \text{CO} \] - Here, coke (carbon) reduces FeO to iron (Fe) while producing carbon monoxide (CO). 4. **Reduction of Fe2O3 Below 1073 K**: - At temperatures below 1073 K, carbon monoxide (CO) is used as the reducing agent. The reaction can be represented as: \[ \text{Fe}_2\text{O}_3 + 3\text{CO} \rightarrow 2\text{Fe} + 3\text{CO}_2 \] - In this case, carbon monoxide reduces Fe2O3 to iron (Fe) while producing carbon dioxide (CO2). 5. **Final Answer**: - Therefore, the complete answer to the question is: - Above 1073 K, **coke** reduces FeO to Fe. - Below 1073 K, **carbon monoxide** reduces Fe2O3 to Fe.
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Assertion. Both C and CO can reduce FeO to Fe but at temperatures above 1073 K it is C which is a better reducing agent than CO while below 1073 K, it is CO which is a better reducing agent than C. Reason. Above 1073 K, Delta _f G^(@) for CO from C is more negative than that of FeO from Fe while below 1073 K, Delta _f G^(@)CO_ 2 from CO is more negative that that of FeO from Fe.

Knowledge Check

  • Correct statements form the graph I) Above 1073K, DeltaG^(0) for the formation of Fe_(2)O_(3) is less negative than DeltaG^(0) for the formation of CO from carbon II) Above 1073K, Carbon can reduce Fe_(2)O_(3) III) Below 1073K, CO can reduce Fe_(2)O_(3) IV) In blast furnace, reduction of Fe_(2)O_(3) occurs in different temperature ranges with below 1073K by CO (or) above 1073K by carbon

    A
    Only I
    B
    I, II only
    C
    I, II, III only
    D
    All
  • Correct statements from the graph I) Above 1073 K, DeltaG^(0) for the formation of F_(2)O_(3) is less negative than DeltaG^(0) for the formation of CO from carbon II) Above 1073K, Carbon can reduce Fe_(2)O_(3) III) Below 1073K, CO can reduce Fe_(2)O_(3) IV) In blast furnance, reduction of Fe_(2)CO_(3) occurs in different temperature ranges with below 1073K by CO (or) above 1073 K by carbon

    A
    Only I
    B
    I,II only
    C
    I,II,III only
    D
    All
  • Correct statements from the graph I) Above 1073 K, DeltaG^(0) for the formation of F_(2)O_(3) is less negative than DeltaG^(0) for the formation of CO from carbon II) Above 1073K, Carbon can reduce Fe_(2)O_(3) III) Below 1073K, CO can reduce Fe_(2)O_(3) IV) In blast furnance, reduction of Fe_(2)CO_(3) occurs in different temperature ranges with below 1073K by CO (or) above 1073 K by carbon

    A
    Only I
    B
    I,II only
    C
    I,II,III only
    D
    All
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