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An unknown compound A (Mn(x)O(y)) compo...

An unknown compound A `(Mn_(x)O_(y))` composed of manganese and oxygen , has 36.7% oxygen by weight. When 8.7 g of A is heated with HCl it liberates `Cl_(2)` gas as per the following reaction:
`Mn_(x)O_(y) +HCl rarr MnCl_(2)+Cl_(2)+H_(2)O` (unbalanced)
The volume of `Cl_(2)` gas at STP obtained when 8.7 gm of compound A is heated with excess of HCl , (assume molecular formula and , empirical formula to be same):

A

1.135 L

B

2.27 L

C

4.54 L

D

0.567 L

Text Solution

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The correct Answer is:
B
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Knowledge Check

  • An unknown compound A (Mn_(x)O_(y)) composed of manganese and oxygen , has 36.7% oxygen by weight. When 8.7 g of A is heated with HCl it liberates Cl_(2) gas as per the following reaction: Mn_(x)O_(y) +HCl rarr MnCl_(2)+Cl_(2)+H_(2)O (unbalanced) The simplest formula of A is:

    A
    MnO
    B
    `MnO_(2)`
    C
    `Mn_(2)O_(3)`
    D
    `Mn_(3)O_(4)`
  • In the reaction MnO_(2)+4HCl to MnCl_(2)+2H_(2)O+Cl_(2)

    A
    `MnO_(2)` is being reduced to `MnCl_(2)`
    B
    HCl is being reduced to `Cl_(2)`
    C
    `MnO_(2)` is acting as a reducing agent
    D
    HCl is an oxidant
  • In the following reaction 2I- + Cr_(2)O_(7)^(2-)+14H^(+) rarr I_(2)+2Cl^(3)+7H_(2)O Unbalanced parts are

    A
    `H^(+)`, `H_(2)O`
    B
    `Cr_(2)O_(7)^(2-)`, `Cr^(3+)`
    C
    `I^(-)`, `I_(2)`
    D
    None of them are balanced
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