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In metal carbonyls, there is synergic bo...

In metal carbonyls, there is synergic bonding interaction between metal and carbon monoxide. This leads to increase in strength of metal ligands bond and decrease in bond order of CO in carbonyl complex as compared to bond order in carbon monoxide.
Simple carbonyls are invariably spin-paired complexes except for vanadium metal.
The increase in bond length in CO as compared to carbon monoxide is due to :

A

the donation of lone pair of electrons from the carbon into a vacant orbital of the metla atom.

B

the donation of a pair of electrons form a filled d-orbital of metal into the vacant antibonding `pi^(**)` orbital of carbon monoxide.

C

(a) and (b) both

D

none.

Text Solution

Verified by Experts

The correct Answer is:
B
Cr' has greater electron density than 'W' due to small size. Hence Cr is a better `pi`-donor.
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In metal carbonyls, there is synergic bonding interaction between metal and carbon monoxide.This leads to increase in strength of metal ligand bond and decrease in bond order of CO in carbonyl complex as compared to bond order in carbon monoxide. Simple carbonyls are invariably spin-paired complexes except for vanadium metal. Which one of the following metal carbonyls involves the d^2sp^3 hybridisation for the formation of metal-carbon sigma bonds and is paramagnetic ?

In metal carbonyls, there is synergic bonding interaction between metal and carbon monoxide. This leads to increase in strength of metal ligands bond and decrease in bond order of CO in carbonyl complex as compared to bond order in carbon monoxide. Simple carbonyls are invariably spin-paired complexes except for vanadium metal. Which one of the following metal carbonyl involves the d^(2)sp^(3) hybridization for the formation of metal-carbon sigma" "bonds and is paramagnetic ?

Knowledge Check

  • In metal carbonyls, there is synergic bonding interaction between metal and carbon monoxide.This leads to increase in strength of metal ligand bond and decrease in bond order of CO in carbonyl complex as compared to bond order in carbon monoxide. Simple carbonyls are invariably spin-paired complexes except for vanadium metal. In metal carbonyls, the increase in C-O bond length in CO as compared to carbon monoxide is due to :

    A
    The donation of lone pair of electrons on the carbon into a vacant orbital of the metal atom
    B
    The donation of a pair of electrons from a filled d-orbital of metal into the vacant antibonding `pi` orbital of carbon monoxide
    C
    (A) and (B) both
    D
    None

  • In metal carbonyls, there is synergic bonding interaction between metal and carbon monoxide. This leads to increase in strength of metal ligands bond and decrease in bond order of CO in carbonyl complex as compared to bond order in carbon monoxide. Simple carbonyls are invariably spin-paired complexes except for vanadium metal. Which of the following statement is correct for metal carbonyls ?

    A
    In general, the effective atomic number for a stable monomeric of the next inert gas except `[V(CO)_(6)]`.
    B
    The metal-carbon bond in metal carbonyls posses both s and p character.
    C
    The C-O bond length in `[Cr(CO)_(6)]` is greater than that in `[W(CO)_(6)]`
    D
    All of these

  • In metal carbonyls, there is synergic bonding interaction between metal and carbon monoxide. This leads to increase in strength of metal ligands bond and decrease in bond order of CO in carbonyl complex as compared to bond order in carbon monoxide. Simple carbonyls are invariably spin-paired complexes except for vanadium metal. Which of the following statement is correct for metal carbonyls ?

    A
    In general, the effective atomic number for a stable monomeric of the next inert gas except `[V(CO)_(6)]`.
    B
    The metal-carbon bond in metal carbonyls posses both s and p character.
    C
    The C-O bond length in `[Cr(CO)_(6)]` is greater than that in `[W(CO)_(6)]`
    D
    All of these

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    In metal carbonyls, there is synergic bonding interaction between metal and carbon monoxide. This leads to increase in strength of metal ligands bond and decrease in bond order of CO in carbonyl complex as compared to bond order in carbon monoxide. Simple carbonyls are invariably spin-paired complexes except for vanadium metal. Which one of the following metal carbonyl involves the d^(2)sp^(3) hybridization for the formation of metal-carbon sigma" "bonds and is paramagnetic ?

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