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Sidgwick EAN rule says that complex com...

Sidgwick EAN rule says that complex compound has the tendency to achieve the EAN of 36, 54 and 86 for first, second and third transition series elements.
Which of the following complex acts as reducing agent based on Sidgwick EAN rule ?

A

`Mn(CO)_(5)`

B

`Mn_(2)(CO)_(10)`

C

`Mn(CO)_(6)`

D

`[V(CO)_(6)]^(-)`

Text Solution

Verified by Experts

The correct Answer is:
C

`underset(EAN=37)(Mn(CO)_(6)) to underset(EAN=36)(Mn(CO)_(6)^(+)+e^(-))`
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