As originally developed, cystal field theory was used to describe the electronic structure of metal ion crystals, where they are surrounded by oxide ions or other anions that create an electrostatic filed with symmetry dependent on the crystal structure.
If for the complex `K_(4)[FeL_(6)]` the value of `Delta_(0)=22000" "cm^(-1)`. Find out the value of crystal pairing energy. Where L is uninegative monodentate ligand.
As originally developed, cystal field theory was used to describe the electronic structure of metal ion crystals, where they are surrounded by oxide ions or other anions that create an electrostatic filed with symmetry dependent on the crystal structure.
If for the complex `K_(4)[FeL_(6)]` the value of `Delta_(0)=22000" "cm^(-1)`. Find out the value of crystal pairing energy. Where L is uninegative monodentate ligand.
If for the complex `K_(4)[FeL_(6)]` the value of `Delta_(0)=22000" "cm^(-1)`. Find out the value of crystal pairing energy. Where L is uninegative monodentate ligand.
A
`-46200" "cm^(-1)`
B
`-52800" "cm^(-1)`
C
`+2200" "cm^(-1)`
D
`-22200" "cm^(-1)`
Text Solution
Verified by Experts
The correct Answer is:
B
`K_(4)[overset(+2)FeL_(6)] d^(6) to t_(2g)^(2,2,2)eg^(0,0)`
CFSE`=-0.4xx6Delta_(0)=-2.4Delta_(0)`
`implies "CFSE"=-2.4xx22000=-52800 cm^(-1)`
CFSE`=-0.4xx6Delta_(0)=-2.4Delta_(0)`
`implies "CFSE"=-2.4xx22000=-52800 cm^(-1)`
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